The investigation of complexation properties and synthesis of the (salen and salophen)-bridged Fe/Cr(III) capped complexes of novel Schiff bases

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dc.contributor.authorKocyigit, Ozcan
dc.contributor.authorGuler, Ersin
dc.date.accessioned2020-03-26T18:05:20Z
dc.date.available2020-03-26T18:05:20Z
dc.date.issued2010
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThis article describes synthesis of novel Schiff base and its complexation properties with Fe(III) and Cr(III). Firstly 1,3,5-tris (formylphenoxymethyl)benzene (1, TRIPOD) with tris aldehyde groups were synthesized using the 1,3,5-trisbromomethylbenzene and 4-hydroxybezaldehyde. The compound 1 was converted to the Schiff base derivative (2, TCPIM-TRIPOD) with p-aminobenzoic acid. The prepared TCPIM-TRIPOD were reacted with four new trinuclear Fe(III) and Cr(III) complexes involving tetradenta Schiff bases N,N-bis(salicylidene)ethylenediamine-(salenH(2)) or bis(salicylidene)-o-phenylenediamine-(salophenH(2)) and characterized by means of elemental analysis carrying out infrared spectroscopy (IR), thermogravimetric analysis (TG), nuclear magnetic resonance (H-1-NMR), elemental analysis and magnetic susceptibility measurement. The complexes can also be characterized as low-spin distorted octahedral Fe(III) and Cr(III) bridged by carboxylic acids. The tricarboxylic acids play a role as bridges for weak antiferromagnetic intramolecular exchange.en_US
dc.description.sponsorshipFoundation of Selcuk UniversitySelcuk University [2006-06101042]en_US
dc.description.sponsorshipWe thank the Scientific Research Projects Foundation of Selcuk University (SUBAP-Grant Number 200606101042) for financial support of this work produced from a part of O. Kocyigit's PhD Thesis.en_US
dc.identifier.doi10.1007/s10847-009-9664-0en_US
dc.identifier.endpage37en_US
dc.identifier.issn1388-3127en_US
dc.identifier.issn1573-1111en_US
dc.identifier.issue01.02.2020en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage29en_US
dc.identifier.urihttps://dx.doi.org/10.1007/s10847-009-9664-0
dc.identifier.urihttps://hdl.handle.net/20.500.12395/25393
dc.identifier.volume67en_US
dc.identifier.wosWOS:000277340700005en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSPRINGERen_US
dc.relation.ispartofJOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectComplexationen_US
dc.subjectTrisaldehydeen_US
dc.subjectSchiff baseen_US
dc.subjectTrisbromomethylbenzeneen_US
dc.titleThe investigation of complexation properties and synthesis of the (salen and salophen)-bridged Fe/Cr(III) capped complexes of novel Schiff basesen_US
dc.typeArticleen_US

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