Fe(II/III) adsorption onto styrene/divinyl benzene based polymers

Küçük Resim Yok

Tarih

2007

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

JOHN WILEY & SONS INC

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

The effectiveness of two styrene/divinyl benzene (SDB) compounds was studied for the removal of Fe(II) and Fe(III) from aqueous solutions. The first one was styrene/divinyl benzene sulfonate (SDB-S), which was commercially supplied and used as an ion-exchange resin. The second one was a terpolymer, styrene/divinyl benzene/allyl methacrylate (SDBAM), which was synthesized from the monomers and used as an adsorbent. Fe(II/III) removal experiments were conducted in columns and in batch reactors. The results indicated that both SDB compounds were effective for both Fe(II) and Fe(III) removal. The ion-exchange capacity of SDB-S was calculated to be 907 mequiv/100 g for Fe(II) and 1100 mequiv/100 g for Fe(III) (which are good quantities). The adsorptive capacity of SDBAM, determined from isotherm calculations, was 79 mequiv/100 g for Fe(II) and 70 mequiv/100 g for Fe(III). This was less than the adsorptive capacity of SDB-S but acceptable in comparison with common adsorbents. The SDB compounds were more selective for Fe(II). (c) 2007 Wiley Periodicals, Inc.

Açıklama

Anahtar Kelimeler

adsorption, ion exchangers, radical polymerization, waste

Kaynak

JOURNAL OF APPLIED POLYMER SCIENCE

WoS Q Değeri

Q3

Scopus Q Değeri

Q2

Cilt

104

Sayı

4

Künye