Fe(II/III) adsorption onto styrene/divinyl benzene based polymers
Küçük Resim Yok
Tarih
2007
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
JOHN WILEY & SONS INC
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The effectiveness of two styrene/divinyl benzene (SDB) compounds was studied for the removal of Fe(II) and Fe(III) from aqueous solutions. The first one was styrene/divinyl benzene sulfonate (SDB-S), which was commercially supplied and used as an ion-exchange resin. The second one was a terpolymer, styrene/divinyl benzene/allyl methacrylate (SDBAM), which was synthesized from the monomers and used as an adsorbent. Fe(II/III) removal experiments were conducted in columns and in batch reactors. The results indicated that both SDB compounds were effective for both Fe(II) and Fe(III) removal. The ion-exchange capacity of SDB-S was calculated to be 907 mequiv/100 g for Fe(II) and 1100 mequiv/100 g for Fe(III) (which are good quantities). The adsorptive capacity of SDBAM, determined from isotherm calculations, was 79 mequiv/100 g for Fe(II) and 70 mequiv/100 g for Fe(III). This was less than the adsorptive capacity of SDB-S but acceptable in comparison with common adsorbents. The SDB compounds were more selective for Fe(II). (c) 2007 Wiley Periodicals, Inc.
Açıklama
Anahtar Kelimeler
adsorption, ion exchangers, radical polymerization, waste
Kaynak
JOURNAL OF APPLIED POLYMER SCIENCE
WoS Q Değeri
Q3
Scopus Q Değeri
Q2
Cilt
104
Sayı
4