Synthesis of novel chiral Schiff base and amino alcohol derivatives of calix[4]arene and chiral recognition properties
dc.contributor.author | Erdemir, Serkan | |
dc.date.accessioned | 2020-03-26T18:31:30Z | |
dc.date.available | 2020-03-26T18:31:30Z | |
dc.date.issued | 2012 | |
dc.department | Selçuk Üniversitesi | en_US |
dc.description.abstract | In the present study, the synthesis and liquid phase extraction properties towards some amino acid methylesters and amino alcohols of Schiff base and amino alcohol substituted calix[4]arene are reported. The Schiff base substituted calix(4]arene 5 has been synthesized via condensation reaction involving 5,17-diformyl-11,23-di-tert-butyl-25,27-di[3-(4-formylphenoxy)propoxy]-26,28 dihydroxycalix[4]arene 4 and (R)-(-)-2-phenylglycine methyl ester in CHCl3:MeOH. To give the amino alcohol substituted calix[4]arene 6, the synthesized chiral compound 5 was reduced by LiAlH4. The new chiral Schiff base and amino alcohol derivatives of calix[4]arene have been characterized by a combination of FT-IR, H-1 NMR, C-13 NMR, FAB-MS and elemental analysis. Also, the extraction behaviors of 5 and 6 towards some selected amino acid methylesters and amino alcohols have been studied by liquid-liquid extraction. (C) 2011 Elsevier B.V. All rights reserved. | en_US |
dc.description.sponsorship | Research Foundation of The Selcuk University (BAP)Selcuk University | en_US |
dc.description.sponsorship | We thank the Research Foundation of The Selcuk University (BAP) for financial support of this work. | en_US |
dc.identifier.doi | 10.1016/j.molstruc.2011.10.053 | en_US |
dc.identifier.endpage | 241 | en_US |
dc.identifier.issn | 0022-2860 | en_US |
dc.identifier.scopusquality | Q2 | en_US |
dc.identifier.startpage | 235 | en_US |
dc.identifier.uri | https://dx.doi.org/10.1016/j.molstruc.2011.10.053 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12395/28462 | |
dc.identifier.volume | 1007 | en_US |
dc.identifier.wos | WOS:000300076200031 | en_US |
dc.identifier.wosquality | Q3 | en_US |
dc.indekslendigikaynak | Web of Science | en_US |
dc.indekslendigikaynak | Scopus | en_US |
dc.language.iso | en | en_US |
dc.publisher | ELSEVIER SCIENCE BV | en_US |
dc.relation.ispartof | JOURNAL OF MOLECULAR STRUCTURE | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.selcuk | 20240510_oaig | en_US |
dc.subject | Calix[4]arene | en_US |
dc.subject | Chiral | en_US |
dc.subject | Amino acid methylesters | en_US |
dc.subject | Amino alcohol | en_US |
dc.subject | Liquid phase extraction | en_US |
dc.title | Synthesis of novel chiral Schiff base and amino alcohol derivatives of calix[4]arene and chiral recognition properties | en_US |
dc.type | Article | en_US |
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