Synthesis of novel chiral Schiff base and amino alcohol derivatives of calix[4]arene and chiral recognition properties

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dc.contributor.authorErdemir, Serkan
dc.date.accessioned2020-03-26T18:31:30Z
dc.date.available2020-03-26T18:31:30Z
dc.date.issued2012
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractIn the present study, the synthesis and liquid phase extraction properties towards some amino acid methylesters and amino alcohols of Schiff base and amino alcohol substituted calix[4]arene are reported. The Schiff base substituted calix(4]arene 5 has been synthesized via condensation reaction involving 5,17-diformyl-11,23-di-tert-butyl-25,27-di[3-(4-formylphenoxy)propoxy]-26,28 dihydroxycalix[4]arene 4 and (R)-(-)-2-phenylglycine methyl ester in CHCl3:MeOH. To give the amino alcohol substituted calix[4]arene 6, the synthesized chiral compound 5 was reduced by LiAlH4. The new chiral Schiff base and amino alcohol derivatives of calix[4]arene have been characterized by a combination of FT-IR, H-1 NMR, C-13 NMR, FAB-MS and elemental analysis. Also, the extraction behaviors of 5 and 6 towards some selected amino acid methylesters and amino alcohols have been studied by liquid-liquid extraction. (C) 2011 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipResearch Foundation of The Selcuk University (BAP)Selcuk Universityen_US
dc.description.sponsorshipWe thank the Research Foundation of The Selcuk University (BAP) for financial support of this work.en_US
dc.identifier.doi10.1016/j.molstruc.2011.10.053en_US
dc.identifier.endpage241en_US
dc.identifier.issn0022-2860en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage235en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.molstruc.2011.10.053
dc.identifier.urihttps://hdl.handle.net/20.500.12395/28462
dc.identifier.volume1007en_US
dc.identifier.wosWOS:000300076200031en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherELSEVIER SCIENCE BVen_US
dc.relation.ispartofJOURNAL OF MOLECULAR STRUCTUREen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectCalix[4]areneen_US
dc.subjectChiralen_US
dc.subjectAmino acid methylestersen_US
dc.subjectAmino alcoholen_US
dc.subjectLiquid phase extractionen_US
dc.titleSynthesis of novel chiral Schiff base and amino alcohol derivatives of calix[4]arene and chiral recognition propertiesen_US
dc.typeArticleen_US

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