Synthesis of p-tert-butylcalix[4]arene dinitrile bonded aminopropyl silica and investigating its usability as a stationary phase in HPLC

Küçük Resim Yok

Tarih

2006

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

TAYLOR & FRANCIS INC

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

The chromatic separation of adenine, adenosine, cytosine, phenol, benzene, and toluene were investigated by using 5,11,17,23-tert-butyl-25,27-bis(cyanomethoxy)-26-(chloroformyl)-28-hydroxy-calix[4]arene bonded aminopropyl silica (CDBAPS) as a stationary phase. The separation ability of the stationary phase was observed to be good for target species. The effect of non-polar calix[n]arene network was observed in chromatographic processes, and it was thought that, thanks to the relatively polar nitrile groups, further selectivity would be obtained in various chromatographic separations.

Açıklama

Anahtar Kelimeler

calixarene, immobilization, aminopropyl silica, HPLC, nucleo bases, nucleosides, aromatic compounds

Kaynak

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY

WoS Q Değeri

N/A

Scopus Q Değeri

Q2

Cilt

A43

Sayı

2

Künye