Synthesis and complexation of two new phenylaminoglyoxime ligands
Küçük Resim Yok
Tarih
2008
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
TAYLOR & FRANCIS LTD
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Two new soluble phenylaminoglyoxime ligands, 4-isopropylanilinephenylglyoxime ((LH2)-H-1), 4-benzylpiperidinephenylglyoxime ((LH2)-H-2), were prepared by reacting 4-isopropylaniline and 4-benzylpiperidine with chlorophenylglyoxime. Mononuclear nickel(II), cobalt(II), copper(II), zinc(II), and cadmium(II) complexes with these ligands were synthesized. On the basis of the magnetic and spectral evidence a square-planar geometry for Ni(II) and Cu(II) complexes, a tedrahedral geometry for Cd(II) and Zn(II) complexes and octahedral geometry for Co(II) complexes are proposed. These compounds were elucidated by elemental analysis, IR, UV-Vis, and magnetic moments. The ligands were additionally characterized by H-1 NMR and C-13 NMR spectra.
Açıklama
Anahtar Kelimeler
phenylaminoglyoxime, 4-isopropylaniline, 4-benzylpiperidine, transition metal complexes
Kaynak
JOURNAL OF COORDINATION CHEMISTRY
WoS Q Değeri
Q3
Scopus Q Değeri
Q3
Cilt
61
Sayı
6
