Synthesis and characterization of 4-(alkylaminoisonitrosoacetyl)diphenyl ether and some of their metal complexes
Küçük Resim Yok
Tarih
2008
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
4-(Chloroacetyl)diphenyl ether (I) was synthesized from chloroacetyl chloride and diphenyl ether in the presence of AlCl3 as catalyst in a Friedel-Crafts reaction. Subsequently, its keto oxime (II) derivative was prepared. Then 3 new substituted 4-(alkylaminoisonitrosoacetyl)diphenyl ether ligands derived from 4-(phenoxy)phenyloxylohydroxymoyl chloride and corresponding amines were synthesized. The following aromatic and aliphatic amines were used for the ligands ethanolamine, 2-amino-4-methylphenol, and 2-(aminomethyl) pyridine. Mononuclear or binuclear Co(II), Ni(II), Cu(II), and Cd(II) complexes of the ligands were synthesized. The structures of these ligands were identified by FT-IR, 1H-NMR, and 13CNMR spectral data and elemental analysis, and the structures of the complexes were identified by FT-IR, ICP-AES, elemental analysis, and magnetic susceptibility measurements. © TÜBİAK.
Açıklama
Anahtar Kelimeler
Binuclear complexes, Ketoxime, Transition metal complexes
Kaynak
Turkish Journal of Chemistry
WoS Q Değeri
Scopus Q Değeri
Q3
Cilt
32
Sayı
3
