Synthesis and characterization of 4-(alkylaminoisonitrosoacetyl)diphenyl ether and some of their metal complexes

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dc.contributor.authorCoşkun A.
dc.contributor.authorYilmaz F.
dc.date.accessioned2020-03-26T17:29:07Z
dc.date.available2020-03-26T17:29:07Z
dc.date.issued2008
dc.departmentSelçuk Üniversitesien_US
dc.description.abstract4-(Chloroacetyl)diphenyl ether (I) was synthesized from chloroacetyl chloride and diphenyl ether in the presence of AlCl3 as catalyst in a Friedel-Crafts reaction. Subsequently, its keto oxime (II) derivative was prepared. Then 3 new substituted 4-(alkylaminoisonitrosoacetyl)diphenyl ether ligands derived from 4-(phenoxy)phenyloxylohydroxymoyl chloride and corresponding amines were synthesized. The following aromatic and aliphatic amines were used for the ligands ethanolamine, 2-amino-4-methylphenol, and 2-(aminomethyl) pyridine. Mononuclear or binuclear Co(II), Ni(II), Cu(II), and Cd(II) complexes of the ligands were synthesized. The structures of these ligands were identified by FT-IR, 1H-NMR, and 13CNMR spectral data and elemental analysis, and the structures of the complexes were identified by FT-IR, ICP-AES, elemental analysis, and magnetic susceptibility measurements. © TÜBİAK.en_US
dc.identifier.endpage312en_US
dc.identifier.issn1300-0527en_US
dc.identifier.issue3en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage305en_US
dc.identifier.urihttps://hdl.handle.net/20.500.12395/22914
dc.identifier.volume32en_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.relation.ispartofTurkish Journal of Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectBinuclear complexesen_US
dc.subjectKetoximeen_US
dc.subjectTransition metal complexesen_US
dc.titleSynthesis and characterization of 4-(alkylaminoisonitrosoacetyl)diphenyl ether and some of their metal complexesen_US
dc.typeArticleen_US

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