Improvement of wetting properties of expanded perlite particles by an organic conformal coating
Küçük Resim Yok
Tarih
2018
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
ELSEVIER SCIENCE SA
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Expanded perlite particles were surface functionalized using poly(hydroxyethyl methacrylate) (PHEMA) thin film under radio frequency (RF) plasma conditions in a rotating-bed plasma enhanced chemical vapor deposition (PECVD) system. Using a rotating-bed system allowed effective agitation and mixing of the particles during depositions, which ensure uniform surface coating of highly porous and particulate materials. The effects of plasma power and plasma operation mode, namely pulsed and continuous modes on the deposition rates, structure, wettability and water holding capacities of expanded perlite particles were investigated. Chemical and morphological properties of uncoated and coated expanded perlites were determined by SEM, FUR, contact angle, and BET analyses. Observed deposition rates changed between 10 and 35 nm/min., which were dependent on the deposition conditions. It was found that pulsing the discharge helped to minimize undesirable monomer fragmentation while providing better film structure. The most hydrophilic PHEMA thin films were fabricated at 50 W plasma power and under pulsed-plasma mode. When the expanded perlite was modified with PHEMA under suitable experimental conditions, the water holding capacity of untreated particles is increased by more than twenty percent.
Açıklama
Anahtar Kelimeler
Surface coating, Plasma polymerization, PECVD, Expanded perlite, Hydrophilic coating
Kaynak
PROGRESS IN ORGANIC COATINGS
WoS Q Değeri
Q1
Scopus Q Değeri
Q1
Cilt
120