The Novel Triazine Cored Tripodal and Trinuclear Schiff Base-Oxime Metal Complexes: Their Magnetic Properties and Thermal Decompositions

Basit Öğe Kaydı
dc.contributor.authorUysal, Saban
dc.contributor.authorCoskun, Ahmet
dc.date.accessioned2020-03-26T18:17:03Z
dc.date.available2020-03-26T18:17:03Z
dc.date.issued2011
dc.departmentSelçuk Üniversitesien_US
dc.description.abstract2,4,6-tris(4-hydroxybenzimino)-1,3,5-triazine [ 1,2] (III) have been synthesized by the reaction of 1 equiv melamine and three equiv 4-hydroxybenzaldehyde, and characterized by means of elemental analysis, H-1-NMR (nuclear magnetic resonance spectroscopy), Fourier transform infrared (FTIR) spectrscopy, liquid chromatography-mass spectroscopy (LC-MS). L (IV) has been synthesized by the reaction of one equiv (III) and three equiv 4-(thiophenoxy) phenyloxylohydroxymoyl chloride (II), and characterized by means of the same methods. Then, four novel trinuclear Fe(III) and Cr(III) complexes involving tetradentate Schiff bases N,N'-bis(salicylidene)ethylenediamine-(salenH(2)) or bis(salicylidene)-o-phenylenediamine-(salophen H-2) with L (IV) have been synthesized and characterized by means of elemental analysis, FTIR spectrscopy, LC-MS, thermal analyses. The metal ratios of the prepared complexes have been determined using AAS. The aim of the present study is synthesis of novel tridirectional-trinuclear systems and to present their effects on magnetic behavior of [salenFe(III)], [salophenFe(III)], [salenCr(III)], and [salophenCr(III)] capped complexes. The complexes have also been characterized as low-spin distorted octahedral Fe(III) and Cr(III) bridged by keton-oxime group.en_US
dc.identifier.doi10.1002/jhet.671en_US
dc.identifier.endpage941en_US
dc.identifier.issn0022-152Xen_US
dc.identifier.issn1943-5193en_US
dc.identifier.issue4en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage936en_US
dc.identifier.urihttps://dx.doi.org/10.1002/jhet.671
dc.identifier.urihttps://hdl.handle.net/20.500.12395/26970
dc.identifier.volume48en_US
dc.identifier.wosWOS:000293745900031en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWILEYen_US
dc.relation.ispartofJOURNAL OF HETEROCYCLIC CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.titleThe Novel Triazine Cored Tripodal and Trinuclear Schiff Base-Oxime Metal Complexes: Their Magnetic Properties and Thermal Decompositionsen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu