Synthesis of novel silica gel immobilized-calix[4]arene amide ionophores and their anion binding abilities toward phosphate and chromate anions

Yükleniyor...
Küçük Resim

Tarih

2012

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

WILEY-BLACKWELL

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

This article describes the synthesis and characterization of four new calix[4]arene ionophores 57 and 9 and corresponding two new silica gel-immobilized calix[4]arene ionophores containing pyridine 10 and 11 via modification of calix[4]arene monoamide derivatives 5 and 6 with aminopropyl silica gel, respectively. The extraction studies have been performed using liquidliquid extraction for receptors 57 and 9 and solidliquid batchwise sorption procedures for receptors 10 and 11. Obtained extraction results showed that the immobilized-calix[4] arene ionophores 10 and 11 have high extraction ability toward chromate and phosphate anions as compared to their corresponding monomeric precursors 5 and 6. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012

Açıklama

Anahtar Kelimeler

dichromate, phosphate, calix[4]arene, sorption, immobilized calixarene

Kaynak

JOURNAL OF APPLIED POLYMER SCIENCE

WoS Q Değeri

Q2

Scopus Q Değeri

Q2

Cilt

124

Sayı

5

Künye