Development of New Electrochemical Surfaces for the Detection of Metals in Waste Water

Basit Öğe Kaydı
dc.contributor.authorOztekin Y.
dc.contributor.authorYazicigil Z.
dc.contributor.authorDuran T.
dc.contributor.authorDumrul H.
dc.contributor.authorGuler E.
dc.contributor.authorKocyigit O.
dc.date.accessioned2020-03-26T18:06:01Z
dc.date.available2020-03-26T18:06:01Z
dc.date.issued2010
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractIn this study, electrochemical experiments were performed in non-aqueous media in order to determine electrochemical behavior of some of the glyoxime derivatives (GDs). Phenylglyoxime (PG), p-chloro-phenylglyoxime (p-CPG), and 1,2-phenylendiamino-p-chlorophenylglyoxime (PACPG) were chosen as GDs. Pt wire, Ag/Ag+ (in 0.01 M AgNO3) and glassy carbon (GC) electrode were used as counter, reference, and working electrode, respectively. The multiscan cyclic voltammograms (CVs) of these compounds were registered in acetonitrile (MeCN) containing 0.1 M tetrabutylammonium tetrafluoroborat (TBATFB) at scan rate of 100 mV/s. The potential was swept from 0 to +2.0 V versus Ag/Ag+ (0.01 M). The CVs of GDs were compared with each other and the electrochemical behaviors of the compounds were investigated depending on the functional groups in their structures. The electrochemical characterization of these modified surfaces was performed and characterizations were compared with the chatacterization results of bare GC surfaces. The application areas for new surfaces were investigated. These results will be active in the disciplines of electrochemistry and industrial physical chemistry, and in related industrial fields at the dissemination of new information for scientific area.Determination of trace metals in waste water is based on the modification of solid electrode surfaces with glyoxime derivatives in order to form effective surfaces. The main force of the here described method is an easy and successfully application to environmental samples. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.en_US
dc.identifier.doi10.1002/clen.200900293en_US
dc.identifier.endpage926en_US
dc.identifier.issn1863-0650en_US
dc.identifier.issue10en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage921en_US
dc.identifier.urihttps://dx.doi.org/10.1002/clen.200900293
dc.identifier.urihttps://hdl.handle.net/20.500.12395/25603
dc.identifier.volume38en_US
dc.identifier.wosWOS:000837045900001en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.relation.ispartofClean - Soil, Air, Wateren_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectElectrochemical modificationen_US
dc.subjectGlassy carbonen_US
dc.subjectGlyoxime derivativesen_US
dc.subjectMetal detectionen_US
dc.titleDevelopment of New Electrochemical Surfaces for the Detection of Metals in Waste Wateren_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

Scopus İndeksli Yayınlar Koleksiyonu
WoS İndeksli Yayınlar Koleksiyonu