Fabrication of thin films of phosphonated calix[4]arene bearing crown ether and their gas sensing properties

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dc.authorid0000-0003-1080-4590
dc.authorid0000-0003-4440-1896
dc.authorid0000-0001-5117-9168
dc.contributor.authorCapan, Inci.
dc.contributor.authorBayrakci, Mevlut.
dc.contributor.authorErdogan, Matem.
dc.contributor.authorOzmen, Mustafa.
dc.date.accessioned2020-03-26T20:14:15Z
dc.date.available2020-03-26T20:14:15Z
dc.date.issued2019
dc.departmentSelçuk Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.description.abstractCalix[4]arenes bearing phosphate and crown ether groups are shown to hold considerable promise as the active layer in volatile organic compound (VOC) vapor sensor. Its chemical sensing selectivity and sensitivity can be altered by different alkyl side chains. These organic architectures were successfully deposited by the spin coating method on gold-coated glass surfaces. Surface plasmon resonance technique was used for VOCs detection to evaluate the chemical-sensing properties of these calix[4]arene derivatives. Spun thin films of calix[4]arene derivatives were exposed to a variety of VOC vapors, and the resonance angles changes of these films were recorded for the specific analyte vapors, such as chloroform, carbon tetrachloride, dichloromethane, ethanol, benzene, and toluene. Measurements were made at room temperature, and the responses were found to be fast and appeared to be completely reversible. The sensing results showed similar response patterns, and our data strongly indicate that response of used thin films of calix[4]arene derivatives to chloroform is much higher than those of an y other VOCs used with the values of 0.47 x 10(-3), 1.042 x 10(-3), and 1.952 x 10(-3) (% / ppm) for the compounds 1, 2, and 3, respectively. Furthermore, gas sensing interaction mechanisms of the thin films were evaluated in terms of the molar volumes, dipole moments, and refractive indexes of the analyzed gas molecules.en_US
dc.description.sponsorshipResearch Foundation of Selcuk UniversitySelcuk University [16611114]; Research Foundation of Karamanoglu Mehmetbey University [25-M-15]en_US
dc.description.sponsorshipThis work was supported in part by the Research Foundation of Selcuk University under Grant 16611114 and in part by the Research Foundation of Karamano. glu Mehmetbey University under Grant 25-M-15. The associate editor coordinating the review of this paper and approving it for publication was Dr. Camilla Baratto.en_US
dc.identifier.citationCapan, I., Bayrakci, M., Erdogan, M., Ozmen, M. (2018). Fabrication of Thin Films of Phosphonated Calix [4] Arene Bearing Crown Ether and Their Gas Sensing Properties. IEEE Sensors Journal, 19(3), 838-845.
dc.identifier.doi10.1109/JSEN.2018.2878840en_US
dc.identifier.endpage845en_US
dc.identifier.issn1530-437Xen_US
dc.identifier.issn1558-1748en_US
dc.identifier.issue3en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage838en_US
dc.identifier.urihttps://dx.doi.org/10.1109/JSEN.2018.2878840
dc.identifier.urihttps://hdl.handle.net/20.500.12395/37846
dc.identifier.volume19en_US
dc.identifier.wosWOS:000456165700006en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorOzmen, Mustafa.
dc.language.isoenen_US
dc.publisherIEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INCen_US
dc.relation.ispartofIEEE SENSORS JOURNALen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectCalixareneen_US
dc.subjectgas sensingen_US
dc.subjectSPRen_US
dc.subjectthin filmen_US
dc.titleFabrication of thin films of phosphonated calix[4]arene bearing crown ether and their gas sensing propertiesen_US
dc.typeArticleen_US

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