Facile and Rapid Synthesis of Microwave Assisted Pd Nanoparticles as Non-Enzymatic Hydrogen Peroxide Sensor

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dc.contributor.authorSahin, Ozlem
dc.contributor.authorKivrak, Hilal
dc.contributor.authorKivrak, Arif
dc.contributor.authorKazici, Hilal Celik
dc.contributor.authorAlal, Orhan
dc.contributor.authorAtbas, Dilan
dc.date.accessioned2020-03-26T19:41:46Z
dc.date.available2020-03-26T19:41:46Z
dc.date.issued2017
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractCarbon supported Pd catalyst was prepared with microwave-assisted polyol method (M-Pd@C) and investigated sensing activity for non-enzymatic hydrogen peroxide (H2O2). Moreover, M-Pd@C and Pd@C catalyst which synthesized via polyol method (P-Pd@C) were compared to each other in terms of electrocatalytic activity. X-ray diffraction (XRD), X-ray photo electron spectroscopy (XPS), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were used to investigate structural and morphological properties of these catalysts. Furthermore, electrochemical measurements were performed via cyclic voltammetry (CV), chronoamperometry (CA) techniques. CV results exhibited that M-Pd/C catalyst showed perfect electrocatalytic activity in terms of reduction of H2O2. M-Pd/C catalyst showed a fast response of less than 7 s with a linear range of 5.0x10(-3)-11.0 mM and a relatively low detection limit of 1.2 mu M amperometric response. M-Pd/C catalyst exhibited great selectivity for detecting H2O2 in the existence of several hindering species such as uric acid and ascorbic acid.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) projectTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [113Z249, 114M156, 114Z042]en_US
dc.description.sponsorshipCHI 660E potentiostat employed in electrochemical measurements was purchased from The Scientific and Technological Research Council of Turkey (TUBITAK) project (project no: 113Z249). The chemicals were purchased from TUBITAK project (Project no: 114M156). Anton Paar monowave reactor was purchased from TUBITAK project (project no: 114Z042). XRD measurements were performed at Selcuk University central laboratory. XPS and TEM measurements were conducted at METU central laboratory.en_US
dc.identifier.doi10.20964/2017.01.26en_US
dc.identifier.endpage769en_US
dc.identifier.issn1452-3981en_US
dc.identifier.issue1en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage762en_US
dc.identifier.urihttps://dx.doi.org/10.20964/2017.01.26
dc.identifier.urihttps://hdl.handle.net/20.500.12395/35126
dc.identifier.volume12en_US
dc.identifier.wosWOS:000396470000064en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherESGen_US
dc.relation.ispartofINTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCEen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectPd nanoparticlesen_US
dc.subjectmicrowave assisted polyol methoden_US
dc.subjectnon-enzymaticen_US
dc.subjecthydrogen peroxide sensoren_US
dc.titleFacile and Rapid Synthesis of Microwave Assisted Pd Nanoparticles as Non-Enzymatic Hydrogen Peroxide Sensoren_US
dc.typeArticleen_US

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