Preparation and Spectral and Biological Investigation of vic-Dioxime Ligands Containing Piperazine Moiety and Their Mononuclear Transition-Metal Complexes

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dc.contributor.authorTaner, Bilge
dc.contributor.authorArslan, Ugur
dc.date.accessioned2020-03-26T18:42:59Z
dc.date.available2020-03-26T18:42:59Z
dc.date.issued2013
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractTwo vic-dioxime ligands, N-(4-benzylpiperazine-1-yl) p-tolylglyoxime ((LH2)-H-1) and N,N-bis(4-benzylpiperazine-1-yl) glyoxime ((LH2)-H-2), containing piperazine moieties were synthesized, and their Ni(II), Cu(II), Co(II) and Zn(II) complexes were obtained. The ligands were characterized by elemental analysis, Fourier transform-infrared (FT-IR), ultraviolet-visible NMR (H-1, C-13, and heteronuclear multiple-bond correlation), and electrospray ionization (ESI) mass spectrometry. The isolated complexes were characterized by a combination of elemental analysis, IR, UV-vis, and ESI mass spectrometry and in the case of Ni(II) and Zn(II) complexes by H-1 and C-13 NMR spectroscopy. The electrochemical behaviors of the ligands and their complexes were studied by cyclic voltammetry (CV) in dimethylsulfoxide solution containing tetrabutylammoniumtetrafluoroborate (TBATFB). The antibacterial activity was also studied against S. aureus ATCC 25923, S. aureus ATCC 29213, S. mutans RSHM 676, E. faecalis ATCC 29212, E. coli ATCC 25922, and P. aeruginosa ATCC 27853. The antimicrobial test results indicated that all the compounds have good antibacterial activity against P. auriginosa ATCC 27853 bacteria and were as effective as ampicilin. [Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) for the following free supplemental resources: Full experimental and spectral details.]en_US
dc.description.sponsorshipSelcuk UniversitySelcuk University [12401020]en_US
dc.description.sponsorshipThis work was supported the Research Fund of Selcuk University, Project Number 12401020.en_US
dc.identifier.doi10.1080/00397911.2013.777743en_US
dc.identifier.endpage3314en_US
dc.identifier.issn0039-7911en_US
dc.identifier.issn1532-2432en_US
dc.identifier.issue24en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage3307en_US
dc.identifier.urihttps://dx.doi.org/10.1080/00397911.2013.777743
dc.identifier.urihttps://hdl.handle.net/20.500.12395/29746
dc.identifier.volume43en_US
dc.identifier.wosWOS:000323999500009en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherTAYLOR & FRANCIS INCen_US
dc.relation.ispartofSYNTHETIC COMMUNICATIONSen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectAntimicrobial activityen_US
dc.subjectcyclic voltammetryen_US
dc.subject1D and 2D NMRen_US
dc.subjectpiperazineen_US
dc.subjectvic-dioximeen_US
dc.titlePreparation and Spectral and Biological Investigation of vic-Dioxime Ligands Containing Piperazine Moiety and Their Mononuclear Transition-Metal Complexesen_US
dc.typeArticleen_US

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