One-pot synthesis of gold nanoparticles using tetradentate porphyrins

Küçük Resim Yok

Tarih

2011

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

SPRINGER

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

In this study, the meso-tetra (p-hydroxyphenyl) porphyrin and meso-tetra (m-hydroxyphenyl) porphyrin were coated on to gold nanoparticles (AuNPs) via thioacetate anchors which easily dissociate to form S-Au bonds. 4-tert-butyl phenyl thioacetate-AuNPs were prepared and used as a monodentate passivant to control the size of the tetradentate porphyrin-AuNPs. The porphyrin-coated AuNPs were characterized by UV-Vis, TEM, XRD, and XPS analyses. The tetradentate porphyrin-AuNPs size is within a range of 5-15 nm in diameter with exotic shapes. The plausible network formation for AuNP@p-TPP-SAc and the capping structure of the AuNP@m-TPP-SAc have been suggested.

Açıklama

Anahtar Kelimeler

Porphyrin, Gold nanoparticles, Thioacetate, XPS, TEM, Biomedical applications

Kaynak

JOURNAL OF NANOPARTICLE RESEARCH

WoS Q Değeri

Q1

Scopus Q Değeri

Q2

Cilt

13

Sayı

12

Künye