One-pot synthesis of gold nanoparticles using tetradentate porphyrins
Küçük Resim Yok
Tarih
2011
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
SPRINGER
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
In this study, the meso-tetra (p-hydroxyphenyl) porphyrin and meso-tetra (m-hydroxyphenyl) porphyrin were coated on to gold nanoparticles (AuNPs) via thioacetate anchors which easily dissociate to form S-Au bonds. 4-tert-butyl phenyl thioacetate-AuNPs were prepared and used as a monodentate passivant to control the size of the tetradentate porphyrin-AuNPs. The porphyrin-coated AuNPs were characterized by UV-Vis, TEM, XRD, and XPS analyses. The tetradentate porphyrin-AuNPs size is within a range of 5-15 nm in diameter with exotic shapes. The plausible network formation for AuNP@p-TPP-SAc and the capping structure of the AuNP@m-TPP-SAc have been suggested.
Açıklama
Anahtar Kelimeler
Porphyrin, Gold nanoparticles, Thioacetate, XPS, TEM, Biomedical applications
Kaynak
JOURNAL OF NANOPARTICLE RESEARCH
WoS Q Değeri
Q1
Scopus Q Değeri
Q2
Cilt
13
Sayı
12