The (salophen)-bridged Fe/Cr (III) capped complexes with triphenylene core: Synthesis and characterization

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dc.contributor.authorKocyigit, Ozcan
dc.contributor.authorGuler, Ersin
dc.date.accessioned2020-03-26T18:16:31Z
dc.date.available2020-03-26T18:16:31Z
dc.date.issued2011
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThis article describes synthesis of the difference carboxylic acid derivatives of triphenylene and its complexation properties with Fe/Cr (III)-salophen. For this purpose, the carboxylic acid derivatives of 2,3,6,7,10,11-hexahydroxytriphenylene were synthesized and then reacted with four new Fe(III) and Cr(III) complexes involving tetradenta Schiff bases bis(salicylidene)-o-phenylenediamine-(salophenH(2)). The prepared compounds were characterized by means of elemental analysis carrying out infrared spectroscopy (IR), thermogravimetric analysis (TG), nuclear magnetic resonance (H-1 NMR), elemental analysis and magnetic susceptibility measurement. The complexes can also be characterized as low-spin distorted octahedral Fe(III) and Cr (III) bridged by carboxylic acids. (C) 2011 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipScientific Research Projects Foundation of Selcuk UniversitySelcuk University [2006-06101042]en_US
dc.description.sponsorshipWe thank the Scientific Research Projects Foundation of Selcuk University (SUBAP-Grant Number 2006-06101042) for financial support of this work produced from a part of O. Kocyigit's PhD Thesis.en_US
dc.identifier.doi10.1016/j.jorganchem.2011.06.020en_US
dc.identifier.endpage3112en_US
dc.identifier.issn0022-328Xen_US
dc.identifier.issn1872-8561en_US
dc.identifier.issue19en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage3106en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.jorganchem.2011.06.020
dc.identifier.urihttps://hdl.handle.net/20.500.12395/26884
dc.identifier.volume696en_US
dc.identifier.wosWOS:000293281900010en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherELSEVIER SCIENCE SAen_US
dc.relation.ispartofJOURNAL OF ORGANOMETALLIC CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectComplexationen_US
dc.subjectTriphenyleneen_US
dc.subjectCarboxylic aciden_US
dc.subjectSalophenen_US
dc.titleThe (salophen)-bridged Fe/Cr (III) capped complexes with triphenylene core: Synthesis and characterizationen_US
dc.typeArticleen_US

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