Bronsted acidic magnetic nano-Fe3O4-adorned calix[n]arene sulfonic acids: synthesis and application in the nucleophilic substitution of alcohols
Küçük Resim Yok
Tarih
2014
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
PERGAMON-ELSEVIER SCIENCE LTD
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Three magnetically recoverable Bronsted acidic calix[n]arene derivatives were successfully constructed by immobilizing calix[n]arene sulfonic acids onto silica-coated magnetic nanoparticles, a process, which allows calix[n]arene derivatives to acquire magnetic properties. All of the magnetically recoverable Bronsted acidic calix[n]arenes efficiently catalyze the coupling of electron-rich arenes with some alcohols in water. After separation and recovery from the reaction mixture by a simple magnet, these Bronsted acidic calix[n]arenes can be recycled many times without losing their catalytic activity. (C) 2014 Elsevier Ltd. All rights reserved.
Açıklama
Anahtar Kelimeler
Calix[n]arene sulfonic acids, Magnetic nanoparticles, Bronsted acid catalysis, Alkylation of aromatic compounds, Green chemistry
Kaynak
TETRAHEDRON
WoS Q Değeri
Q2
Scopus Q Değeri
Q2
Cilt
70
Sayı
37