Kinetic Study of Mercury (II) Transport Through a Liquid Membrane Containing Calix[4]arene Nitrile Derivatives as a Carrier in Chloroform

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dc.contributor.authorGübbük, İ. Hilal
dc.contributor.authorGüngör, Ömer
dc.contributor.authorAlpoğuz, Hamza Korkmaz
dc.contributor.authorErsöz, Mustafa
dc.contributor.authorYılmaz, Mustafa
dc.date.accessioned2020-03-26T17:49:23Z
dc.date.available2020-03-26T17:49:23Z
dc.date.issued2010
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractIn this study, the kinetics studies of mercury (II) ion transport through a bulk liquid membrane system which contains calix[4]arene nitrile derivatives (5,11,17,23-Tetra-tert-butyl-25,27-bis-(2-cyanobenzyloxy)-26,28-dihydroxycalix-[4]arene (membrane I) and 25,27-bis-(2-cyanomethoxy)-26,28-dihydroxycalix-Harene (membrane II) as a membrane were investigated at different temperatures and stirring rates. The kinetics was analyzed by means of a kinetic model involving two consecutive irreversible first order reactions. The parameters such as transport rate constants, membrane entrance rate, k(1), and the membrane exit rate, k(2), and the maximum values for membrane entrance and exit values J(d)(max) and J(a)(max) determined for the experimental data. It was found that both membrane entrance and exit rate constants increase with temperature. The activation energies were found as 6.96 +/- 0.15 and 6.91 +/- 0.15 kcal/mol, for ligand membranes land II, respectively. These activation values indicate that the transport process for both membranes is controlled by species diffusion.en_US
dc.description.sponsorshipScientific Research Projects Foundation of Selcuk University (SUBAP)Selcuk University [FBE 05701008, 2003/182]en_US
dc.description.sponsorshipThe authors are grateful for the financial support provided by the Scientific Research Projects Foundation of Selcuk University (SUBAP) under project FBE 05701008 and 2003/182.en_US
dc.identifier.citationGübbük, İ. H., Güngör, Ö., Alpoğuz, H. K., Ersöz, M., Yılmaz, M., (2010). Kinetic Study of Mercury (II) Transport Through a Liquid Membrane Containing Calix[4]arene Nitrile Derivatives as a Carrier in Chloroform. Desalination, 261, 157-161. doi:10.1016/j.desal.2010.05.011
dc.identifier.doi10.1016/j.desal.2010.05.011en_US
dc.identifier.endpage161en_US
dc.identifier.issn0011-9164en_US
dc.identifier.issue01.02.2020en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage157en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.desal.2010.05.011
dc.identifier.urihttps://hdl.handle.net/20.500.12395/25032
dc.identifier.volume261en_US
dc.identifier.wosWOS:000281060100022en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorGübbük, İ. Hilal
dc.institutionauthorErsöz, Mustafa
dc.institutionauthorYılmaz, Mustafa
dc.language.isoenen_US
dc.publisherELSEVIER SCIENCE BVen_US
dc.relation.ispartofDesalinationen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectMetal transport with mercury (II)en_US
dc.subjectLiquid membranesen_US
dc.subjectTransport kineticsen_US
dc.subjectCalixareneen_US
dc.titleKinetic Study of Mercury (II) Transport Through a Liquid Membrane Containing Calix[4]arene Nitrile Derivatives as a Carrier in Chloroformen_US
dc.typeArticleen_US

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