Synthesis and characterization of novel nanofiber based calixarene and its binding efficiency towards chromium and uranium ions

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dc.contributor.authorÖzcan, Fatih
dc.contributor.authorBayrakcı, Mevlüt
dc.contributor.authorErtul, Şeref
dc.date.accessioned2020-03-26T19:26:42Z
dc.date.available2020-03-26T19:26:42Z
dc.date.issued2016
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThe objective of this study is to obtain nanofibrous precursor based calixarene with high ion adsorption capacity by electrospinning of blended solution of polyacrylonitrile (PAN) and upper rim functionalized calix[4]arene bearing N-methylglucamine (Calix-NMG). The obtained electrospun fibers were characterized using fourier transform infrared (FT-IR-ATR), scanning electron microscope (SEM) equipped with energy-dispersive X-ray spectrometry (EDX) and thermogravimetric analyses (TGA and DSC). Analysis indicated that preparation of nanofibers based Calix-NMG was successfully achieved. The ion binding studies exhibited that the nanofiber based Calix-NMG could be efficiently used for the binding of chromate anions and uranium cations. Nanofiber based calix[4]arene with N-methylglucamine chelating groups may be a good candidate as a filter material for treatment of a large quantity of wastewater owing to their very large surface area as well as both the inclusion and donor-acceptor complexation capability of all surfaces associated with the calixarene skeleton.en_US
dc.description.sponsorshipSelcuk UniversitySelcuk University; Karamanoglu Mehmetbey University Research FoundationKaramanoglu Mehmetbey University [25-M-15]en_US
dc.description.sponsorshipThe authors gratefully would like to thank Selcuk University and Karamanoglu Mehmetbey University Research Foundation (Project No: 25-M-15) for financial support.en_US
dc.identifier.doi10.1007/s10847-016-0604-5en_US
dc.identifier.endpage58en_US
dc.identifier.issn1388-3127en_US
dc.identifier.issn1573-1111en_US
dc.identifier.issue01.02.2020en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage49en_US
dc.identifier.urihttps://dx.doi.org/10.1007/s10847-016-0604-5
dc.identifier.urihttps://hdl.handle.net/20.500.12395/34043
dc.identifier.volume85en_US
dc.identifier.wosWOS:000376021800004en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSPRINGERen_US
dc.relation.ispartofJOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectCalixareneen_US
dc.subjectNanofiberen_US
dc.subjectN-methylglucamineen_US
dc.subjectUraniumen_US
dc.subjectChromateen_US
dc.titleSynthesis and characterization of novel nanofiber based calixarene and its binding efficiency towards chromium and uranium ionsen_US
dc.typeArticleen_US

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