Cu(II) sorption performance of novel chitosan/ter-(vinyl pivalate-maleic anhydride-N-tert-butylacrylamide) microcapsules

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dc.contributor.authorOkudan, Ahmet.
dc.contributor.authorAtaoglu, Busra Ebru.
dc.contributor.authorSengoz, Onur.
dc.contributor.authorArslan, Gulsin.
dc.date.accessioned2020-03-26T20:13:12Z
dc.date.available2020-03-26T20:13:12Z
dc.date.issued2019
dc.departmentSelçuk Üniversitesi, Fen Fakültesi, Kimya Bölümüen_US
dc.description.abstractIn this study, first, the ter-polymerization reaction between vinyl pivalate (VP), maleic anhydride (MA), and N-tert-butylacrylamide (NTBA) was done in inert atmosphere (N-2). FT-IR and (HNMR)-H-1 spectroscopy was applied to study the chemical composition of the obtained ter-polymers. MA content of the ter-polymers was determined by following the chemical titration method. Second, novel chitosan/ter-(vinyl-pivalate-maleic-anhydride-N-tert-butylacrylamide) microcapsules were synthesized. In microcapsule production, chitosan polymer served as a matrix for acrylamide ter-polymers with four different molar ratios. The microcapsules were characterized by FT-IR and SEM analyses. Cu(II) sorption efficiency of the microcapsules were tested at different pH levels, temperature, sorbent dosage, and metal ion concentration. Comparison with blank chitosan microbeads revealed that incorporation of acrylamide ter-polymers into the cross-linked chitosan matrix increased the metal sorption. Sorption capacities of the sorbents were recorded; blank chitosan microbeads: 67.03 mg g(-1), and chitosan/acrylamide ter-polymer microcapsules: in range of 75.39-98.64 mg g(-1). The findings demonstrated chitosan/acrylamide ter-polymer microcapsules can be utilized in sorption of Cu(II) ions in water treatment.en_US
dc.description.sponsorshipSelcuk University Research FoundationSelcuk University [BAP-13201026]en_US
dc.description.sponsorshipThis study presented was supported by Selcuk University Research Foundation (Project Number BAP-13201026).en_US
dc.identifier.citationOkudan, A., Ataoglu, B. E., Sengoz, O., Arslan, G. (2019). Cu (II) Sorption Performance of Novel Chitosan/Ter-(vinyl pivalate-maleic anhydride-N-tert-butylacrylamide) Microcapsules. Journal of Polymers and the Environment, 27(11), 2454-2463.
dc.identifier.doi10.1007/s10924-019-01535-7en_US
dc.identifier.endpage2463en_US
dc.identifier.issn1566-2543en_US
dc.identifier.issn1572-8919en_US
dc.identifier.issue11en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage2454en_US
dc.identifier.urihttps://dx.doi.org/10.1007/s10924-019-01535-7
dc.identifier.urihttps://hdl.handle.net/20.500.12395/37643
dc.identifier.volume27en_US
dc.identifier.wosWOS:000491549500014en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorOkudan, Ahmet.
dc.institutionauthorAtaoglu, Busra Ebru.
dc.institutionauthorSengoz, Onur.
dc.institutionauthorArslan, Gulsin.
dc.language.isoenen_US
dc.publisherSPRINGERen_US
dc.relation.ispartofJOURNAL OF POLYMERS AND THE ENVIRONMENTen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectAdsorptionen_US
dc.subjectAcrylamideen_US
dc.subjectTer-polymeren_US
dc.subjectMicrocapsuleen_US
dc.subjectWater treatmenten_US
dc.titleCu(II) sorption performance of novel chitosan/ter-(vinyl pivalate-maleic anhydride-N-tert-butylacrylamide) microcapsulesen_US
dc.typeArticleen_US

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