Application of Cr(VI) Transport through the Polymer Inclusion Membrane with a New Synthesized Calix[4]arene Derivative

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dc.contributor.authorKaya, Ahmet
dc.contributor.authorAlpoğuz, Hamza Korkmaz
dc.contributor.authorYılmaz, Aydan
dc.date.accessioned2020-03-26T18:41:08Z
dc.date.available2020-03-26T18:41:08Z
dc.date.issued2013
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractFacilitated transport of Cr(VI) ions from aqueous chromate donor phase (2.10(-4) kmol/m(3)) through polymer inclusion membranes (PIMs) using a new synthesized 5,17-di-tert-butyl-11-piperidinomethyl-25,26,27,28-tetrahydroxycalix[4]arene (carrier), as ion carrier, has been investigated. The Cr(VI) passed through a PIM comprised of cellulose triacetate (CTA) as a support and 2-NPOE as a plasticizer. The prepared PIM was characterized with Fourier transform infrared (FT-IR) spectroscopy and the atomic force microscopy (AFM) techniques as well as with contact angle measurements. The efficiency of Cr(VI) transport through the PIM was investigated by studying the effects of carrier concentration on the donor phase as well as by measuring the amount of plasticizer in the membrane, the pH in the acceptor phase, the effect of acid type in donor phase, and the membrane's stability and thickness. The kinetic parameters were calculated as permeability coefficient (P), flux (J), and diffusion coefficient (D). The transport efficiency of Cr(VI) was observed to be 99.38% after 6 h under optimized conditions. These results indicated that PIMs can be used in the long term for the removal of Cr(VI) from industrial waste waters.en_US
dc.description.sponsorshipScientific Research Projects (BAP) of Pamukkale University, Denizli-TurkeyPamukkale University [2012 FBE 064]en_US
dc.description.sponsorshipThis work was supported by the Scientific Research Projects (BAP) of Pamukkale University, Denizli-Turkey (2012 FBE 064).en_US
dc.identifier.doi10.1021/ie303257wen_US
dc.identifier.endpage5436en_US
dc.identifier.issn0888-5885en_US
dc.identifier.issue15en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage5428en_US
dc.identifier.urihttps://dx.doi.org/10.1021/ie303257w
dc.identifier.urihttps://hdl.handle.net/20.500.12395/29229
dc.identifier.volume52en_US
dc.identifier.wosWOS:000317873200019en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherAMER CHEMICAL SOCen_US
dc.relation.ispartofINDUSTRIAL & ENGINEERING CHEMISTRY RESEARCHen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.titleApplication of Cr(VI) Transport through the Polymer Inclusion Membrane with a New Synthesized Calix[4]arene Derivativeen_US
dc.typeArticleen_US

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