Synthesis, characterization and electrochemical investigation of a novel vic-dioxime ligand and its some transition metal complexes

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dc.contributor.authorCoşkun, Ahmet
dc.contributor.authorYılmaz, Funda
dc.contributor.authorAkgemci, Emine Güler
dc.date.accessioned2020-03-26T17:27:56Z
dc.date.available2020-03-26T17:27:56Z
dc.date.issued2008
dc.departmentSelçuk Üniversitesien_US
dc.description.abstract4-(Chloroacetyl)diphenyl ether was synthesized from chloroacetyl chloride and diphenyl ether in the presence of AlCl3 as catalyst in a Friedel-Crafts reaction. Then, its keto oxime and dioxime derivatives were prepared. 4-phenoxy-(N-4-chlorophenylamino)phenylglyoxime (H2L) was synthesized from 4-(phenoxy)chlorophenylglyoxime and 4-chloroaniline. Ni(II), Co(II) and Cu(II) complexes of H2L were obtained. The mononuclear Ni(II), Co(II) and Cu(II) complexes of H2L have a metal-ligand ratio of 1:2 and the ligand coordinates through the two N atoms, as do most of the vic-dioximes. The structure of the ligand was identified by FT-IR, H-1 NMR, C-13 NMR, C-13 NMR (APT) spectroscopy and elemental analysis data. The structures of the complexes were characterized on the basis of FT-IR, ICP-AES, UV-Vis, elemental analysis, magnetic susceptibility measurements, and cyclic voltammetry. The electrochemical measurements were obtained by using cyclic voltammetry in DMF solution at room temperature. The electrochemical behaviors of H2L and its complexes showed that the redox process of H2L has one irreversible oxidation wave, whereas the redox processes of the complexes have both oxidation and reduction waves with metal centered.en_US
dc.identifier.doi10.1007/s10847-007-9389-xen_US
dc.identifier.endpage400en_US
dc.identifier.issn1388-3127en_US
dc.identifier.issn1573-1111en_US
dc.identifier.issue03.04.2020en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage393en_US
dc.identifier.urihttps://dx.doi.org/10.1007/s10847-007-9389-x
dc.identifier.urihttps://hdl.handle.net/20.500.12395/22678
dc.identifier.volume60en_US
dc.identifier.wosWOS:000254457800022en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSPRINGERen_US
dc.relation.ispartofJOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectketo oximeen_US
dc.subjectglyoximeen_US
dc.subjecttransition metal complexesen_US
dc.subjectredox propertiesen_US
dc.titleSynthesis, characterization and electrochemical investigation of a novel vic-dioxime ligand and its some transition metal complexesen_US
dc.typeArticleen_US

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