Complexes of Iron(III) and Chromium(III) Salen and Salophen Schiff Bases with Bridging 1,3,5-Triazine Derived Multidirectional Ligands
dc.contributor.author | Koc, Ziya Erdem | |
dc.date.accessioned | 2020-03-26T18:14:00Z | |
dc.date.available | 2020-03-26T18:14:00Z | |
dc.date.issued | 2011 | |
dc.department | Selçuk Üniversitesi | en_US |
dc.description.abstract | A new synthetic route for preparing multidirectional ligands was developed by using 2,4,6-trichloro-1,3,5- triazine (cyanuric chloride) as core. The reaction included the selective substitutions of 4-aminobenzoic acid onto three chlorides of the triazine ring via a stepwise manner at 1:1, 1:2, or 1:3 equiv. and 0, 25, 130 degrees C, respectively. An efficient synthesis of a novel class of "multidirectional ligands'' has been developed based on high-yielding chloride substitutions of 2,4,6-trichloro-1,3,5-triazine by amines. Sixteen new mono-, di-, tri-, and tetra-nuclear Fe(III) and Cr(III) complexes involving tetradenta Schiff bases N,N'-bis(salicylidene)ethylenediamine-(salenH(2)) or bis(salicylidene)-o-phenylenediamine-(salophenH(2)) with two new 1,3,5-triazine derived multidirectional ligands were synthesized and characterized by means of elemental analysis, H-1 NMR, FT-IR spectroscopy, LC-MS analysis, AAS, thermal analysis, and magnetic susceptibility measurements. The complexes were also characterized as low-spin distorted octahedral Fe(III) and Cr(III) bridged by carboxylic acids. It was understood that the [{Fe(salen)/(salophen)}(2)O] and [{Cr(salen)/(salophen)}(2)O] containing compounds could be represented by the electronic structure of t(2g)(6)e(g)(0) and t(2g)(3)e(g)(0). | en_US |
dc.identifier.doi | 10.1002/jhet.577 | en_US |
dc.identifier.endpage | 775 | en_US |
dc.identifier.issn | 0022-152X | en_US |
dc.identifier.issn | 1943-5193 | en_US |
dc.identifier.issue | 4 | en_US |
dc.identifier.scopusquality | Q3 | en_US |
dc.identifier.startpage | 769 | en_US |
dc.identifier.uri | https://dx.doi.org/10.1002/jhet.577 | |
dc.identifier.uri | https://hdl.handle.net/20.500.12395/26267 | |
dc.identifier.volume | 48 | en_US |
dc.identifier.wos | WOS:000293745900003 | en_US |
dc.identifier.wosquality | Q3 | en_US |
dc.indekslendigikaynak | Web of Science | en_US |
dc.indekslendigikaynak | Scopus | en_US |
dc.language.iso | en | en_US |
dc.publisher | WILEY | en_US |
dc.relation.ispartof | JOURNAL OF HETEROCYCLIC CHEMISTRY | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.selcuk | 20240510_oaig | en_US |
dc.title | Complexes of Iron(III) and Chromium(III) Salen and Salophen Schiff Bases with Bridging 1,3,5-Triazine Derived Multidirectional Ligands | en_US |
dc.type | Article | en_US |