Synthesis of Crosslinked Chitosan with Epichlorohydrin Possessing Two Novel Polymeric Ligands and Its Use in Metal Removal

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dc.contributor.authorSahin, Mustafa
dc.contributor.authorKocak, Nuriye
dc.contributor.authorArslan, Gulsin
dc.contributor.authorUcan, Halil Ismet
dc.date.accessioned2020-03-26T18:16:27Z
dc.date.available2020-03-26T18:16:27Z
dc.date.issued2011
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractOne of the major applications of chitosan and its derivatives is based on its ability to bind strongly toxic metal ions. In this work, two novel polymeric ligands were synthesized to investigate the adsorption properties of Cu(II), Pb(II), Zn(II) and Ni(II) ions in an aqueous solution. To prevent the reaction between as the C-2 amine group of chitosan and ECH, the C-2 amine group was protected N-benzylidene chitosan (CTB). After the reaction with ECH to give N-benzaldehyde crosslinked chitosan (CCTB), the Schiff base was removed in a dilute ethanol hydrochloride solution to obtain CCTS which has free amine group. CCTS-ECH was synthesized by the reaction of CCTS and ECH. Then, CCTS-ECH was reacted with (2-hydroxyphenylimino)methylbenzene-1,4-diol (HBD) and N,N'-bis(2,5-dihydroxybenzylidene)-1,4-diaminobenzene (DHDB) to give ligands CCTS-ECH-HBD and CCTS-ECH-DHDB. The batch experiments showed that two novel polymeric ligands can be effectively used to remove Cu(II) from water.en_US
dc.description.sponsorshipSelcuk University Research Foundation (SUAF)Selcuk University [05101005]en_US
dc.description.sponsorshipThe authors are greatly indebted to the Selcuk University Research Foundation (SUAF) for providing financial support (project number: 05101005).en_US
dc.identifier.doi10.1007/s10904-010-9421-2en_US
dc.identifier.endpage80en_US
dc.identifier.issn1574-1443en_US
dc.identifier.issue1en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage69en_US
dc.identifier.urihttps://dx.doi.org/10.1007/s10904-010-9421-2
dc.identifier.urihttps://hdl.handle.net/20.500.12395/26872
dc.identifier.volume21en_US
dc.identifier.wosWOS:000287249700009en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSPRINGERen_US
dc.relation.ispartofJOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALSen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectCrosslinked chitosanen_US
dc.subjectEpichlorohydrineen_US
dc.subjectSchiff baseen_US
dc.subjectRemoval of metalen_US
dc.titleSynthesis of Crosslinked Chitosan with Epichlorohydrin Possessing Two Novel Polymeric Ligands and Its Use in Metal Removalen_US
dc.typeArticleen_US

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