Preparation, Characterization and Modification Kinetics of Modified Polystyrene with Maleic Anhydride

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dc.contributor.authorBaş, Salih Zeki
dc.contributor.authorYıldırım, Mustafa
dc.contributor.authorYıldız, Salih
dc.date.accessioned2020-03-26T18:31:07Z
dc.date.available2020-03-26T18:31:07Z
dc.date.issued2012
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractIn this study, the chemical modification reaction of polystyrene (PS) with maleic anhydride (MA) in the presence of borontrifluoride (BF3) catalyst in chloroform was examined. The modified polystyrene containing (-COCH=CHCOOH) fragments in phenyl rings was characterized by IR and H-1-NMR spectroscopy. In addition, TGA, AFM analyses and contact-angles for polystyrene and the modified polystyrene were performed. The effects of polystyrene concentration, maleic anhydride concentration, catalyst concentration, solvent volume and temperature on the modification reaction were investigated by determining the amount of the carboxyl group fixed to the aromatic ring of polystyrene. Some kinetic parameters such as the reaction rate, the rate constant, the activation energy for the modification reaction were calculated.en_US
dc.description.sponsorshipSelcuk University Research Foundation (BAP)Selcuk University [06201028]en_US
dc.description.sponsorshipThe authors are grateful for the financial support provided by the Selcuk University Research Foundation (BAP) under Project 06201028.en_US
dc.identifier.citationBaş, S. Z., Yıldırım, M., Yıldız, S., (2012). Preparation, Characterization and Modification Kinetics of Modified Polystyrene with Maleic Anhydride. Materiale Plastice, 49(1), 15-19.
dc.identifier.endpage19en_US
dc.identifier.issn0025-5289en_US
dc.identifier.issue1en_US
dc.identifier.scopusqualityQ4en_US
dc.identifier.startpage15en_US
dc.identifier.urihttps://hdl.handle.net/20.500.12395/28334
dc.identifier.volume49en_US
dc.identifier.wosWOS:000303486000004en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorBaş, Salih Zeki
dc.institutionauthorYıldırım, Mustafa
dc.institutionauthorYıldız, Salih
dc.language.isoenen_US
dc.publisherCHIMINFORM DATA S Aen_US
dc.relation.ispartofMateriale Plasticeen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectpolystyreneen_US
dc.subjectmaleic anhydrideen_US
dc.subjectchemical modificationen_US
dc.subjectreaction kineticsen_US
dc.titlePreparation, Characterization and Modification Kinetics of Modified Polystyrene with Maleic Anhydrideen_US
dc.typeArticleen_US

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