Synthesis of Novel Macrocyclic Lactam Based Receptors for Alkali or Transition Metal Cations and Cr2O72- Anions

Küçük Resim Yok

Tarih

2009

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

SLOVENSKO KEMIJSKO DRUSTVO

Erişim Hakkı

info:eu-repo/semantics/openAccess

Özet

The article describes the syntheses and extraction properties of new lactam ionophores. These lactam derivatives were easily synthesized via aminolysis of 2,2'-methylenebis(4-chlorophenol) dimethylester or its corresponding acyl chloride with corresponding diamine compounds in THF or methanol-dichloromethane solvent systems in one step, respectively. The extraction studies of lactam ionophores were performed toward dichromate anion and alkaline and transition metal cations such as Li+, Na+, K+, Co2+, Hg2+ and Pb2+. All the structures of the ionophores were confirmed by spectroscopic techniques and elemental analysis.

Açıklama

Anahtar Kelimeler

Lactam, chromate extraction, picrate extraction, liquid-liquid extraction

Kaynak

ACTA CHIMICA SLOVENICA

WoS Q Değeri

Q3

Scopus Q Değeri

Q3

Cilt

56

Sayı

4

Künye