A Bodipy-bearing pillar[5]arene for mimicking photosynthesis: Multi-fluorophoric light harvesting system

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dc.contributor.authorKursunlu, Ahmed Nuri
dc.contributor.authorBaslak, Canan
dc.date.accessioned2020-03-26T19:52:39Z
dc.date.available2020-03-26T19:52:39Z
dc.date.issued2018
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractHerein, we submitted to the original synthesis, characterization, energy transfer mechanism of the Bodipy-bearing pillar[5]arene Bodipy and its reactants by employing of infrared, H-1, B-11, C-13, F-19- NMRs, UV-vis, fluorescence spectroscopy, melting point apparatus, CHN elemental analysis and mass spectroscopy. Preliminary UV-vis, fluorescence and excitation measurements were carried out in CH2Cl2 and the results revealed an effective fluorescence resonance energy transfer (FRET) system based on the interaction of pillar[5]arene and Bodipy derivative. epsilon(max) of target molecule reached to a maximum value and it was found as 955 000 M-1 cm(-1). This fluorescent macromolecule worked well for mimicking a light harvesting system with an energy transfer efficiency up to 92%. (C) 2018 Elsevier Ltd. All rights reserved.en_US
dc.description.sponsorshipResearch Foundation of Selcuk University (BAP)Selcuk Universityen_US
dc.description.sponsorshipThe authors express their appreciation to Prof. J.-F. Nierengarten and Dr. I. Nierengarten for helpful discussions. Financial support for this work is provided by the Research Foundation of Selcuk University (BAP) and is gratefully acknowledged.en_US
dc.identifier.doi10.1016/j.tetlet.2018.04.016en_US
dc.identifier.endpage1962en_US
dc.identifier.issn0040-4039en_US
dc.identifier.issue20en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage1958en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.tetlet.2018.04.016
dc.identifier.urihttps://hdl.handle.net/20.500.12395/36228
dc.identifier.volume59en_US
dc.identifier.wosWOS:000433014900018en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPERGAMON-ELSEVIER SCIENCE LTDen_US
dc.relation.ispartofTETRAHEDRON LETTERSen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectPillar[5]areneen_US
dc.subject8odipyen_US
dc.subjectLight harvestingen_US
dc.subjectEnergy transferen_US
dc.subjectFluorescenceen_US
dc.titleA Bodipy-bearing pillar[5]arene for mimicking photosynthesis: Multi-fluorophoric light harvesting systemen_US
dc.typeArticleen_US

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