Synthesis of N '-[4 '-Benzo(15-crown-5)]-4-Tolylaminoglyoxime and N '-[4 '-Benzo(15-crown-5)]-4-Chlorophenylaminoglyoxime and Their Complexes With Copper (Ii), Nickel (Ii) and Cobalt (Ii)
Yükleniyor...
Dosyalar
Tarih
2003
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Springer
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
N'-[4'-benzo(15-crown-5)]-4-tolylaminoglyoxime (H2L1), the sodium chloride salt of H2L1 (H2L1.NaCl), N'-[4'-benzo(15-crown-5)]-4-chlorophenylaminoglyoxime (H2L2) and the sodium chloride salt of H2L2 (H2L2.NaCl) have been prepared from p-chlorophenylchloroglyoxime, p-tolylchloroglyoxime, 4'-aminobenzo[15-crown-5] and sodium bicarbonate or sodium bicarbonate and sodium chloride. Nickel (II), cobalt (II) and copper (II) complexes of H2L and H2L.NaCl have a metal-ligand ratio of 1:2 and the ligand coordinates through the two N atoms, as do most of the vic-dioximes. Their IR spectra and elemental analyses are given, together with H-1 NMR spectra of the ligands.
Açıklama
Anahtar Kelimeler
Crown ether, Hlyoximes, Oximes, Transition metal complexes
Kaynak
Journal of Inclusion Phenomena and Macrocyclic Chemistry
WoS Q Değeri
Q2
Scopus Q Değeri
Q3
Cilt
47
Sayı
Künye
Karapınar, E., Özcan, E., (2003). Synthesis of N '-[4 '-Benzo(15-crown-5)]-4-Tolylaminoglyoxime and N '-[4 '-Benzo(15-crown-5)]-4 Chlorophenylaminoglyoxime and Their Complexes With Copper (Ii), Nickel (Ii) and Cobalt (Ii). Journal of Inclusion Phenomena and Macrocyclic Chemistry, (47), 59-63. Doi: 10.1023/B:JIPH.0000003926.35770.2c
