Novel vic-dioxime ligand containing calix[4]pyrrole moiety: synthesis, characterization, anion binding studies and complexation with Ni(II)

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dc.contributor.authorTaner, Bilge
dc.date.accessioned2020-03-26T18:51:48Z
dc.date.available2020-03-26T18:51:48Z
dc.date.issued2014
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractA new vic-dioxime functionalized calix[4] pyrrole was synthesized from anti-chloroglyoxime and 4-aminophenyl-calix[4] pyrrole at room temperature. The Ni(II) complex has been prepared by reacting the ligand with NiCl2 center dot 6H(2)O in ethanol. These receptors were characterized by elemental analyses, H-1 and C-13 NMR spectra, IR and mass spectra. Electrochemical properties of the ligand, and its Ni(II) complex were investigated in CH2Cl2 solution by cyclic voltammetry at 100 mV s(-1) scan rate. Anion-binding studies were carried out using UV-Vis, and 1 H NMR titrations, revealed that the Ni(II) complex exhibits selective recognition toward F- over other anions. The selectivity for F- among the halides is attributed mainly to the hydrogen-bond interaction of the receptor with F-. Receptor showed colour change from red to brown in the presence of tetrabutylammonium fluoride (TBAF) with 1:2 stoichiometry.en_US
dc.description.sponsorshipSelcuk UniversitySelcuk Universityen_US
dc.description.sponsorshipThis work was supported by the Research Fund of Selcuk University.en_US
dc.identifier.doi10.1007/s10847-013-0326-xen_US
dc.identifier.endpage81en_US
dc.identifier.issn1388-3127en_US
dc.identifier.issn1573-1111en_US
dc.identifier.issue01.02.2020en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage75en_US
dc.identifier.urihttps://dx.doi.org/10.1007/s10847-013-0326-x
dc.identifier.urihttps://hdl.handle.net/20.500.12395/31029
dc.identifier.volume79en_US
dc.identifier.wosWOS:000339273600006en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSPRINGERen_US
dc.relation.ispartofJOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectvic-Dioximeen_US
dc.subjectNickel complexen_US
dc.subjectCalix[4]pyrroleen_US
dc.subjectAnion bindingen_US
dc.subjectCyclic voltammetryen_US
dc.titleNovel vic-dioxime ligand containing calix[4]pyrrole moiety: synthesis, characterization, anion binding studies and complexation with Ni(II)en_US
dc.typeArticleen_US

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