Immobilization of cyclic alkylamine calix[4]arene derivatives on merrifield resin: Evaluation of extraction ability toward dichromate
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Date
2006
Journal Title
Journal ISSN
Volume Title
Publisher
TAYLOR & FRANCIS INC
Access Rights
info:eu-repo/semantics/closedAccess
Abstract
Two new calix[4]arene-based polymeric resins were synthesized via nucleophilic substitution reactions involving 5,11,17,23-tetrakis(N-piperidinomethyl)-25,26,27,28-tetrahydroxycalix[4]arene ( 2 ) and 5,11,17,23-tetrakis[4-carboethoxy-N-piperidino]-25,26,27,28-tetrahydroxycalix[4]arene ( 4 ) as precursors with Merrifield resin. Extraction studies were performed by liquid-liquid extraction and solid-liquid adsorption procedures. The monomeric compounds showed excellent extraction ability toward dichromate in liquid-liquid extraction systems. Polymeric resin 3 with calixarene moieties exhibited high adsorption properties, while resin 5 showed lower adsorption of dichromate in solid-liquid extractions.
Description
Keywords
calixarenes, polymers, liquid-liquid extraction, adsorption, dichromate
Journal or Series
JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY
WoS Q Value
N/A
Scopus Q Value
Q2
Volume
A43
Issue
3
