Remediation and liquid-liquid phase transfer extraction of chromium(VI). A review
Küçük Resim Yok
Tarih
2004
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
INST ORGANIC CHEM AND BIOCHEM
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Chromium(VI) is a widely used industrial chemical, and is generally considered to pose a greatest human health risk because it is more toxic, more soluble, and more mobile than chromium(III). Workers in industries that use chromium, in particular stainless steel welding, chromate production, chromium plating, and chrome pigment industries, where exposure via inhalation of aerosols is primarily to hexavalent chromium, are at increased risk of chromium effects. In this article we demonstrate various studies regarding remediation methods in particular liquid-liquid extraction of chromate and dichromate anions with various functionalized calixarenes. This review article briefly discusses various molecular designs of calixarene-type macrocycles for chromium(VI) oxoanion recognition, and gives examples on the relationship between structure and selectivity. The article does not, however, attempt to cover all of the different approaches to chromium(VI) extraction. A review with 73 references.
Açıklama
Anahtar Kelimeler
calixarenes, liquid-liquid extraction, ion recognition, chromium(VI) toxicity, oxoanions, supramolecular chemistry, remediation, chromates
Kaynak
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS
WoS Q Değeri
Q2
Scopus Q Değeri
N/A
Cilt
69
Sayı
6