Synthesis and Characterization of a New Dioxime: Thermal and Magnetic Behavior of Its Heterotrinuclear Bf2+-capped Complexes
Yükleniyor...
Dosyalar
Tarih
2010
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
TAYLOR & FRANCIS LTD
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
New heterotrinuclear complexes have been obtained from dinuclear Fe(III) oxygen-bridged N,N'-bis(salicylidene)ethylenediamine (salenH(2)) and bis(salicylidene)-o-phenylenediamine (salophH(2)) and Co(II), Ni(II), Cu(II) salts. Then, heterotrinuclear vic-dioxime complexes containing BF2+ caps have been synthesized. The complexes have been characterized as low-spin distorted octahedral Fe(III) bridged by COO- groups. The structure of dioxime and its complexes were identified by using elemental analysis, magnetic susceptibility, thermal analysis, ICP-AES, 1H-NMR, and IR spectral data.
Açıklama
Anahtar Kelimeler
BF2+-Capped Complex, Vic-Dioximes, Transition Metal Complexes, Salen, Saloph
Kaynak
Journal of Coordination Chemistry
WoS Q Değeri
Q2
Scopus Q Değeri
Q3
Cilt
63
Sayı
13
Künye
Uysal, Ş., (2010). Synthesis and Characterization of a New Dioxime: Thermal and Magnetic Behavior of Its Heterotrinuclear Bf2+-capped Complexes. Journal of Coordination Chemistry, 63(13), 2370-2378.
DOI: 10.1080/00958972.2010.501106