Synthesis and Characterization of a New Dioxime: Thermal and Magnetic Behavior of Its Heterotrinuclear Bf2+-capped Complexes

Yükleniyor...
Küçük Resim

Tarih

2010

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

TAYLOR & FRANCIS LTD

Erişim Hakkı

info:eu-repo/semantics/openAccess

Özet

New heterotrinuclear complexes have been obtained from dinuclear Fe(III) oxygen-bridged N,N'-bis(salicylidene)ethylenediamine (salenH(2)) and bis(salicylidene)-o-phenylenediamine (salophH(2)) and Co(II), Ni(II), Cu(II) salts. Then, heterotrinuclear vic-dioxime complexes containing BF2+ caps have been synthesized. The complexes have been characterized as low-spin distorted octahedral Fe(III) bridged by COO- groups. The structure of dioxime and its complexes were identified by using elemental analysis, magnetic susceptibility, thermal analysis, ICP-AES, 1H-NMR, and IR spectral data.

Açıklama

Anahtar Kelimeler

BF2+-Capped Complex, Vic-Dioximes, Transition Metal Complexes, Salen, Saloph

Kaynak

Journal of Coordination Chemistry

WoS Q Değeri

Q2

Scopus Q Değeri

Q3

Cilt

63

Sayı

13

Künye

Uysal, Ş., (2010). Synthesis and Characterization of a New Dioxime: Thermal and Magnetic Behavior of Its Heterotrinuclear Bf2+-capped Complexes. Journal of Coordination Chemistry, 63(13), 2370-2378. DOI: 10.1080/00958972.2010.501106