The investigation of nonlinear optical properties of N-(3-fluorophenyl)naphthaldimine
Yükleniyor...
Tarih
2005
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
ELSEVIER SCIENCE BV
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
A new ligand N-(3-fluorophenyl)naphthaldimine (C17H12NOF) has been synthesized. The physical properties and structure of this ligand have been characterized by X-ray diffraction analysis, elemental analysis, FT-IR, H-1-NMR and UV-visible spectroscopies. It is found that the title compound has solvatochromic behavior in the UV and visible regions, implying non-zero microscopic first hyperpolarizability. The electric dipole moment (mu) and the first hyperpolarizability (beta) values of the investigated molecule have been computed using ab initio quantum mechanical calculations (finite field second-order Moller Plesset perturbation theory). The calculation results also reveal that the synthesized molecule might have microscopic nonlinear optical (NLO) behavior with non-zero values. (C) 2004 Elsevier B.V. All rights reserved.
Açıklama
Anahtar Kelimeler
nonlinear optical properties, bathochromic shift, electric dipole moment, first hyperpolarizability, Moller Plesset perturbation theory
Kaynak
JOURNAL OF MOLECULAR STRUCTURE
WoS Q Değeri
Q3
Scopus Q Değeri
Q2
Cilt
737
Sayı
02.03.2020
