Preparation and chromatographic performance of calix[4]crown-5 macrocycle-bonded silica stationary phase

Basit Öğe Kaydı
dc.contributor.authorErdemir, Serkan
dc.contributor.authorYilmaz, Mustafa
dc.date.accessioned2020-03-26T18:15:45Z
dc.date.available2020-03-26T18:15:45Z
dc.date.issued2011
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractA new calix[4]crown-5 macrocycle-bonded silica stationary phase (CL-CIMS) was prepared and applied at the same time to develop a chromatographic procedure to separate aromatic amines, phenols and drugs in this study. The chromatographic behaviors of the prepared stationary phase for these analytes were studied and compared with those of ODS (octadecylsilane). The effect of organic modifier content and pH of the mobile phase on retention and selectivity of these compounds were investigated. Some aromatic amines, phenols or drugs on CL-CIMS were successfully separated. The results show that CL-CIMS exhibits high selectivities for the above analytes in high aqueous mobile phases and a bright prospect in routine, fast separation of aromatic amines, phenols and drug compounds. From chromatographic data, it can be concluded that hydrophobic interaction is mainly responsible for the retention behavior as well as hydrogen-bonding interaction, pi-pi and dipole-dipole interaction.en_US
dc.description.sponsorshipSelcuk UniversitySelcuk University [201010101031]en_US
dc.description.sponsorshipThe authors thank the Scientific Research Projects Foundation of Selcuk University (SUBAP Grant Number 201010101031) for their financial support of this work produced from a part of S. Erdemir's PhD Thesis.en_US
dc.identifier.doi10.1002/jssc.201000690en_US
dc.identifier.endpage401en_US
dc.identifier.issn1615-9306en_US
dc.identifier.issn1615-9314en_US
dc.identifier.issue4en_US
dc.identifier.pmid21254399en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage393en_US
dc.identifier.urihttps://dx.doi.org/10.1002/jssc.201000690
dc.identifier.urihttps://hdl.handle.net/20.500.12395/26744
dc.identifier.volume34en_US
dc.identifier.wosWOS:000287942000005en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherWILEY-V C H VERLAG GMBHen_US
dc.relation.ispartofJOURNAL OF SEPARATION SCIENCEen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectAromatic aminesen_US
dc.subjectCalix[4]crown-5en_US
dc.subjectDrugsen_US
dc.subjectSilica gelen_US
dc.titlePreparation and chromatographic performance of calix[4]crown-5 macrocycle-bonded silica stationary phaseen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
PubMed İndeksli Yayın Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu