Selective Complexation of Na+ by Polymeric Calix[4]arene Tetraesters

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dc.contributor.authorDeligöz, Hasalettin
dc.contributor.authorYılmaz, Mustafa
dc.date.accessioned2020-03-26T16:24:33Z
dc.date.available2020-03-26T16:24:33Z
dc.date.issued1995
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractCalixarenes are readily amenable to chemical modification at the phenolic hydroxy groups, leading to particular, the easy accessibility of p-tert-butyl calix[4]arene has made this member of the series increasingly popular as a building block or platform for assembling more elaborate structures with ligating side arms or podands for the reception of guest species, notably alkali, alkaline earth, and some transition metal cation. For example, the tetraester is sufficiently selective for Na+ to enable its exploitation in ion-selective electrodes. This is attributable to the inner size of the ionophoric cavity composed of four OCH2C = O groups that is comparable with the ion size of Na+, and to the cone conformation that is firmly constructed on the rigid calix[4]arene platform. Until now complexation studies have been conducted with monomeric calixarenes. Polymeric calixarenes are a much more recent innovation. Shinkai, Kawaguchi, and Manabe prepared a calix[6]arene fixed to polystyrene. "Harris, Barrett, and McKervey reported on the polymerization and Na' complexation of calix[4]arene metha~ry1ate.l~ The attachment of calix[4]arene to a polymer support was recently described.en_US
dc.identifier.citationDeligöz, H., Yılmaz, M., (1995). Selective Complexation of Na+ by Polymeric Calix[4]arene Tetraesters. Journal of Polymer Science Part a-Polymer Chemistry, 33(16), 2851-2853.
dc.identifier.doi10.1002/pola.1995.080331619en_US
dc.identifier.endpage2853en_US
dc.identifier.issn0887-624Xen_US
dc.identifier.issue16en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage2851en_US
dc.identifier.urihttps://dx.doi.org/10.1002/pola.1995.080331619
dc.identifier.urihttps://hdl.handle.net/20.500.12395/16297
dc.identifier.volume33en_US
dc.identifier.wosWOS:A1995TB90100019en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorDeligöz, Hasalettin
dc.institutionauthorYılmaz, Mustafa
dc.language.isoenen_US
dc.publisherJohn Wiley & Sons Incen_US
dc.relation.ispartofJournal of Polymer Science Part a-Polymer Chemistryen_US
dc.relation.publicationcategoryDiğeren_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectPOLYMERIC CALIX [4]ARENEen_US
dc.subjectCALIX [4]ARENE TETRAACETATEen_US
dc.subjectSELECTIVE METAL EXTRACTIONen_US
dc.subjectNA+ COMPLEXATIONen_US
dc.subjectPolymeric calix [4]arene
dc.subjectCalix [4]arene tetraacetate
dc.subjectSelective metal extraction
dc.subjectNa+ complexation
dc.titleSelective Complexation of Na+ by Polymeric Calix[4]arene Tetraestersen_US
dc.typeNoteen_US

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