Highly Active Cobalt Sulfide/Carbon Nanotube Catalyst for Hydrogen Evolution at Soft Interfaces

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dc.contributor.authorAslan, Emre
dc.contributor.authorAkin, Ilker
dc.contributor.authorPatir, Imren Hatay
dc.date.accessioned2020-03-26T19:24:30Z
dc.date.available2020-03-26T19:24:30Z
dc.date.issued2016
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractHydrogen evolution at polarized liquid-liquid interfaces [water/1,2-dichloroethane (DCE)] by the electron donor decamethylferrocene (DMFc) is catalyzed efficiently by the fabricated cobalt sulfide (CoS) nanoparticles and nanocomposites of CoS nanoparticles formed on multi-walled carbon nanotubes (CoS/CNT). The suspended CoS/CNT nanocomposite catalysts at the interface show a higher catalytic activity for the hydrogen evolution reaction (HER) than the CoS nanoparticles due to the high dispersity and conductivity of the CNT materials, which can serve as the main charge transport pathways for the injection of electrons to attain the catalytic sites of the nanoparticles. The reaction rate increased more than 1000-fold and 300-fold by using CoS/CNT and CoS catalysts, respectively, when compared to a non-catalyzed reaction.en_US
dc.description.sponsorshipSelcuk University Scientific Research Projects (BAP)Selcuk University [15401115]en_US
dc.description.sponsorshipThe authors would like to thank the Selcuk University Scientific Research Projects (BAP) (Project No: 15401115). The authors declare no competing financial interest.en_US
dc.identifier.doi10.1002/chem.201505048en_US
dc.identifier.endpage5349en_US
dc.identifier.issn0947-6539en_US
dc.identifier.issn1521-3765en_US
dc.identifier.issue15en_US
dc.identifier.pmid26929146en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage5342en_US
dc.identifier.urihttps://dx.doi.org/10.1002/chem.201505048
dc.identifier.urihttps://hdl.handle.net/20.500.12395/33666
dc.identifier.volume22en_US
dc.identifier.wosWOS:000373483600037en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherWILEY-V C H VERLAG GMBHen_US
dc.relation.ispartofCHEMISTRY-A EUROPEAN JOURNALen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectcarbon nanotubesen_US
dc.subjectcobalt sulfideen_US
dc.subjecthydrogen evolutionen_US
dc.subjectliquid-liquid interfacesen_US
dc.titleHighly Active Cobalt Sulfide/Carbon Nanotube Catalyst for Hydrogen Evolution at Soft Interfacesen_US
dc.typeArticleen_US

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