Oxygen Reduction by Decamethylferrocene at Liquid/Liquid Interfaces Catalyzed by Dodecylaniline
Yükleniyor...
Dosyalar
Tarih
2010
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier Science Sa
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Molecular oxygen (O-2) reduction by decamethylferrocene (DMFc) was investigated at a polarized water/1,2-dichloroethane (DCE) interface. Electrochemical results point to a mechanism similar to the EC type reaction at the conventional electrode/solution interface, in which an assisted proton transfer (APT) by DMFc across the water/DCE interface via the formation of DMFcH(+) corresponds to the electrochemical step and O-2 reduction to hydrogen peroxide (H2O2) represents the chemical step. The proton transfer step can also be driven using lipophilic bases such as 4-dodecylaniline. Finally, voltammetric data shows that lipophilic DMFc can also be extracted to the aqueous acidic phase to react homogeneously with oxygen.
Açıklama
Anahtar Kelimeler
Oxygen reduction, Proton reduction, Decamethylferrocene, Liquid/liquid interface, Voltammetry
Kaynak
Journal of Electroanalytical Chemistry
WoS Q Değeri
Q2
Scopus Q Değeri
Q1
Cilt
639
Sayı
01.02.2020
Künye
Su, B., Hatay, İ., Li, F., Partovi-Nia, R., Mendez, M. A., Samec, Z., Ersöz, M., Girault, H. H., (2010). Oxygen Reduction by Decamethylferrocene at Liquid/Liquid Interfaces Catalyzed by Dodecylaniline. Journal of Electroanalytical Chemistry, (639), 102-108. Doi: 10.1016/j.jelechem.2009.11.029
