Oxygen Reduction by Decamethylferrocene at Liquid/Liquid Interfaces Catalyzed by Dodecylaniline

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dc.contributor.authorSu, Bin
dc.contributor.authorHatay, İmren
dc.contributor.authorLi, Fei
dc.contributor.authorPartovi-Nia, Raheleh
dc.contributor.authorMendez, Manuel A.
dc.contributor.authorSamec, Zdenek
dc.contributor.authorErsöz, Mustafa
dc.contributor.authorGirault, Hubert H.
dc.date.accessioned2020-03-26T18:04:47Z
dc.date.available2020-03-26T18:04:47Z
dc.date.issued2010
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractMolecular oxygen (O-2) reduction by decamethylferrocene (DMFc) was investigated at a polarized water/1,2-dichloroethane (DCE) interface. Electrochemical results point to a mechanism similar to the EC type reaction at the conventional electrode/solution interface, in which an assisted proton transfer (APT) by DMFc across the water/DCE interface via the formation of DMFcH(+) corresponds to the electrochemical step and O-2 reduction to hydrogen peroxide (H2O2) represents the chemical step. The proton transfer step can also be driven using lipophilic bases such as 4-dodecylaniline. Finally, voltammetric data shows that lipophilic DMFc can also be extracted to the aqueous acidic phase to react homogeneously with oxygen.en_US
dc.description.sponsorshipEcole Polytechnique Federale de Lausanne (EPFL); Swiss Natural Science Foundation [FNRS 200020-116588]; European Cooperation [D36/007/06]; Scientific and Technological Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK); Agency of the Czech RepublicGrant Agency of the Czech Republic [203/07/1257]en_US
dc.description.sponsorshipThis work was supported by Ecole Polytechnique Federale de Lausanne (EPFL), the Swiss Natural Science Foundation (FNRS 200020-116588) and the European Cooperation in the field of Scientific and Technological Research (COST Action, D36/007/06). I.H. also gratefully acknowledges the Scientific and Technological Research Council of Turkey (TUBITAK) under the 2212-PhD Scholarship Programme. Z.S. is also grateful to the Grant Agency of the Czech Republic (Grant No. 203/07/1257).en_US
dc.identifier.citationSu, B., Hatay, İ., Li, F., Partovi-Nia, R., Mendez, M. A., Samec, Z., Ersöz, M., Girault, H. H., (2010). Oxygen Reduction by Decamethylferrocene at Liquid/Liquid Interfaces Catalyzed by Dodecylaniline. Journal of Electroanalytical Chemistry, (639), 102-108. Doi: 10.1016/j.jelechem.2009.11.029
dc.identifier.doi10.1016/j.jelechem.2009.11.029en_US
dc.identifier.endpage108en_US
dc.identifier.issn1572-6657en_US
dc.identifier.issn1873-2569en_US
dc.identifier.issue01.02.2020en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage102en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.jelechem.2009.11.029
dc.identifier.urihttps://hdl.handle.net/20.500.12395/25142
dc.identifier.volume639en_US
dc.identifier.wosWOS:000275137400015en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.institutionauthorHatay, İmren
dc.institutionauthorErsöz, Mustafa
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofJournal of Electroanalytical Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectOxygen reductionen_US
dc.subjectProton reductionen_US
dc.subjectDecamethylferroceneen_US
dc.subjectLiquid/liquid interfaceen_US
dc.subjectVoltammetryen_US
dc.titleOxygen Reduction by Decamethylferrocene at Liquid/Liquid Interfaces Catalyzed by Dodecylanilineen_US
dc.typeArticleen_US

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