Synthesis of beta-cyclodextrin and starch based polymers for sorption of azo dyes from aqueous solutions

Basit Öğe Kaydı
dc.contributor.authorÖzmen, Elif Yılmaz
dc.contributor.authorSezgin, Mehmet
dc.contributor.authorYılmaz, Aydan
dc.contributor.authorYılmaz, Mustafa
dc.date.accessioned2020-03-26T17:27:54Z
dc.date.available2020-03-26T17:27:54Z
dc.date.issued2008
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThree beta-cyclodextrin (polymers 1-3) and a starch-based (polymer 4) polymers were synthesized using hexamethylene diisocyanate (HMDI) as a cross-linking agent in dry dimethylformamide and used as a sorbent for the removal of some selected azo dyes from aqueous solutions. The cross-linked polymers were characterized by Fourier transform infrared spectroscopy, thermogravimetric and differential scanning calorimetric analysis. Results of sorption showed that cyclodextrin and starch based polymers can be effectively used as a sorbent for the removal of anionic azo dyes. The Influence of the amide groups and the chemical structure of azo dyes are also studied. Results of sorption experiments showed that these adsorbent exhibited high sorption capacities toward Direct Violent 51 (80% for polymer 1, 69% for polymer 2, 70% for polymer 3 and 78% for polymer 4). The sorption capacity of dyes on the polymers was dependent on the presence of sulfonate groups of the anionic dyes. In order to explain the results an adsorption mechanism mainly physical adsorption and interactions such as hydrogen bonding, ion-exchange due to the nature of the polymer network and the formation of an inclusion complex due to the beta-CD molecules through host-guest interaction is proposed. (c) 2007 Elsevier Ltd. All rights reserved.en_US
dc.identifier.doi10.1016/j.biortech.2007.01.023en_US
dc.identifier.endpage531en_US
dc.identifier.issn0960-8524en_US
dc.identifier.issn1873-2976en_US
dc.identifier.issue3en_US
dc.identifier.pmid17350830en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage526en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.biortech.2007.01.023
dc.identifier.urihttps://hdl.handle.net/20.500.12395/22672
dc.identifier.volume99en_US
dc.identifier.wosWOS:000251491200010en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherELSEVIER SCI LTDen_US
dc.relation.ispartofBIORESOURCE TECHNOLOGYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectbeta-cyclodextrin (CD)en_US
dc.subjectstarchen_US
dc.subjectazo dyeen_US
dc.subjectsolid phase extractionen_US
dc.titleSynthesis of beta-cyclodextrin and starch based polymers for sorption of azo dyes from aqueous solutionsen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
PubMed İndeksli Yayın Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu