Synthesis and characterization of a new dioxime and its heterotrinuclear BF(2)(+) capped complexes

Küçük Resim Yok

Tarih

2008

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

TAYLOR & FRANCIS INC

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

omega-Isonitrosoacetophenone (1), phenylglyoxime (2), chlorophenylglyoxime (1), dopaminophenylglyoxime (3) and [(salen/saloph)Fe](2)O (4) have been synthesized as described in the literature procedure. [Fe(III)(salen/saloph)dopaminophenylglyoxime)] (starting complexes) have been synthesized from dopaminophenylglyoxime and tetradentate schiff bases which contain dinuclear Fe(III) oxygen-bridges N,N'-bis(salicylidene)ethylenediamine (salenH(2)) and bis(salicylidene)-o-phenylenediamine (salophH(2)). The new heterotrinuclear complexes have been obtained from starting complexes and Co(II), Ni(II), Cu(II) salts. Then, heterotrinuclear vic-dioxime complexes containing BF(2)(+) capped have been synthesized. The complexes have been characterized as low-spin distorted octahedral Fe(III) bridged by o-hydroxyphenolic groups. The o-hydroxyphenolic groups play a role as bridges for weak antiferromagnetic intramolecular exchange. The structure of dioxime and its complexes were identified by using elemental analysis, ICP-AES, (1)H-NMR and IR spectral data.

Açıklama

Anahtar Kelimeler

BF(2)(+)-capped complex, vic-dioximes, transition metal complexes, salen, saloph

Kaynak

JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY

WoS Q Değeri

Q3

Scopus Q Değeri

Q2

Cilt

45

Sayı

9

Künye