Synthesis and characterization of a new dioxime and its heterotrinuclear BF(2)(+) capped complexes

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dc.contributor.authorUysal, Saban
dc.contributor.authorCoskun, Ahmet
dc.contributor.authorKoc, Ziya Erdem
dc.contributor.authorUcan, H. Ismet
dc.date.accessioned2020-03-26T17:27:51Z
dc.date.available2020-03-26T17:27:51Z
dc.date.issued2008
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractomega-Isonitrosoacetophenone (1), phenylglyoxime (2), chlorophenylglyoxime (1), dopaminophenylglyoxime (3) and [(salen/saloph)Fe](2)O (4) have been synthesized as described in the literature procedure. [Fe(III)(salen/saloph)dopaminophenylglyoxime)] (starting complexes) have been synthesized from dopaminophenylglyoxime and tetradentate schiff bases which contain dinuclear Fe(III) oxygen-bridges N,N'-bis(salicylidene)ethylenediamine (salenH(2)) and bis(salicylidene)-o-phenylenediamine (salophH(2)). The new heterotrinuclear complexes have been obtained from starting complexes and Co(II), Ni(II), Cu(II) salts. Then, heterotrinuclear vic-dioxime complexes containing BF(2)(+) capped have been synthesized. The complexes have been characterized as low-spin distorted octahedral Fe(III) bridged by o-hydroxyphenolic groups. The o-hydroxyphenolic groups play a role as bridges for weak antiferromagnetic intramolecular exchange. The structure of dioxime and its complexes were identified by using elemental analysis, ICP-AES, (1)H-NMR and IR spectral data.en_US
dc.identifier.doi10.1080/10601320802222616en_US
dc.identifier.endpage732en_US
dc.identifier.issn1060-1325en_US
dc.identifier.issue9en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage727en_US
dc.identifier.urihttps://dx.doi.org/10.1080/10601320802222616
dc.identifier.urihttps://hdl.handle.net/20.500.12395/22662
dc.identifier.volume45en_US
dc.identifier.wosWOS:000257526100006en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherTAYLOR & FRANCIS INCen_US
dc.relation.ispartofJOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectBF(2)(+)-capped complexen_US
dc.subjectvic-dioximesen_US
dc.subjecttransition metal complexesen_US
dc.subjectsalenen_US
dc.subjectsalophen_US
dc.titleSynthesis and characterization of a new dioxime and its heterotrinuclear BF(2)(+) capped complexesen_US
dc.typeArticleen_US

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