Synthesis of chiral calix[4]arenes bearing aminonaphthol moieties and their use in the enantiomeric recognition of carboxylic acids

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dc.contributor.authorDurmaz, Mustafa
dc.contributor.authorYılmaz, Mustafa
dc.contributor.authorSirit, Abdülkadir
dc.date.accessioned2020-03-26T18:16:27Z
dc.date.available2020-03-26T18:16:27Z
dc.date.issued2011
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractTwo armed chiral calix[4]arenes 8-16 functionalized at the lower rim with chiral aminonaphthol units have been prepared and the structures of these receptors characterized by FTIR, H-1, and C-13, DEPT and COSY NMR spectroscopy and elemental analysis. The enantioselective recognition of these receptors with various carboxylic acids has been studied by H-1 NMR and UV/Vis spectroscopy. The receptors exhibited different chiral recognition abilities towards the enantiomers of racemic materials and formed 2 : 1 or 1 : 1 complexes between host and guest. It was also demonstrated that chiral calix[4]arenes 9 and 16 could be used as chiral NMR solvating agents to determine the enantiomeric purity of mandelic acid.en_US
dc.description.sponsorshipScientific and Technical Research Council of TurkeyTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [TUBITAK-109T167]; Research Foundation of Selcuk UniversitySelcuk University [BAP-10101005]en_US
dc.description.sponsorshipThis work was supported by the Scientific and Technical Research Council of Turkey (TUBITAK-109T167) and Research Foundation of Selcuk University (BAP-10101005). The provision of PhD studentship to M.D. by TUBITAK-BIDEB is gratefully acknowledged.en_US
dc.identifier.doi10.1039/c0ob00399aen_US
dc.identifier.endpage580en_US
dc.identifier.issn1477-0520en_US
dc.identifier.issn1477-0539en_US
dc.identifier.issue2en_US
dc.identifier.pmid21063630en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage571en_US
dc.identifier.urihttps://dx.doi.org/10.1039/c0ob00399a
dc.identifier.urihttps://hdl.handle.net/20.500.12395/26871
dc.identifier.volume9en_US
dc.identifier.wosWOS:000285749800034en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherROYAL SOC CHEMISTRYen_US
dc.relation.ispartofORGANIC & BIOMOLECULAR CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.titleSynthesis of chiral calix[4]arenes bearing aminonaphthol moieties and their use in the enantiomeric recognition of carboxylic acidsen_US
dc.typeArticleen_US

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