Synthesis and Characterization of Boron Doped Alumina Stabilized Zirconia Fibers
Küçük Resim Yok
Tarih
2011
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
KOREAN FIBER SOC
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Boron doped PVA/Zr-Al acetate nanofibers were prepared by electrospinning using PVA as a precursor. The effect of calcination temperature on morphology and crystal structure was investigated at 250, 500, and 800 degrees C. The study also establishes the effect of boron doping on the morphology of PVA/Zr-Al acetate nanofibers at various calcination temperatures. The measurements showed that the conductivity, pH, viscosity and the surface tension of the hybrid polymer solutions have increased with boron doping. In addition, the fibers were characterized by FTIR, DSC, XPS, XRD and SEM techniques. The addition of boron did not only increase the thermal stability of the fibers, hut also increased the average fiber diameters, which gave stronger fibers. The DSC results indicated that the melting temperature (Tm) of the fibers was increased from 256 to 270 degrees C with the addition of boron. XRD peak patterns showed that after further heat treatment at 800 degrees C, zirconia exists in two phases of tetragonal and monoclinic modifications. Moreover, alumina does not transform into the gamma-Al2O3 and theta-Al2O3 phase at 800 degrees C. The SEM appearance of the fibers showed that the addition of boron resulted in the formation of crosslinked bright surfaced fibers.
Açıklama
Anahtar Kelimeler
Electrospinning, Boric acid, Nanofibers, Zr-Al acetate, PVA
Kaynak
FIBERS AND POLYMERS
WoS Q Değeri
Q2
Scopus Q Değeri
Q2
Cilt
12
Sayı
3
