Fabrication and application of a new modified electrochemical sensor using newly synthesized calixarene-grafted MWCNTs for simultaneous determination of Cu(II) and Pb(II)
Yükleniyor...
Tarih
2019
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
SLOVENSKO KEMIJSKO DRUSTVO
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
A rapid, simple, selective and highly sensitive simultaneous determination of Cu(II) and Pb(II) via newly fashioned 5,11,17,23-tetra-tert-butyl-25,27-dihydrazinamidecarb onylmethoxy-26,28- dihydroxycalix [4] arene-grafted multi-walled carbon nanotubes-modified carbon paste electrode (CNT-Calix/CPE) by differential pulse anodic stripping voltammetry (DPASV) has been introduced. It was observed that CNT-Calix/CPE exhibits higher selectivity and stability for Cu(II) and Pb(II). Different operational parameters such as pH, deposition potential/time, pulse amplitude (5, -1.0 V vs. Ag/AgCl, 300 s, 2 s, 0.05 V) were also optimized for calculation and statistical evaluation of linear range, detection limit and limit of quantification. Interference study shows that the electrode is highly selective for the simultaneous determination of Cu(II) and Pb(II). Standard addition method was used to apply CNT-Calix/CPE in waste water, plant leaves and soft drinks and it was found that the concentration of Cu(II) and Pb(II) were corresponding to standardized values.
Açıklama
Anahtar Kelimeler
Calixarene, MWCNT, modified carbon paste electrode, sensor
Kaynak
ACTA CHIMICA SLOVENICA
WoS Q Değeri
Q3
Scopus Q Değeri
Q3
Cilt
66
Sayı
4
Künye
Kucukkolbasi, S., Sayin, S., Yılmaz, M. (2019). Fabrication and Application of a New Modified Electrochemical Sensor Using Newly Synthesized Calixarene-Grafted MWCNTs for Simultaneous Determination of Cu (II) and Pb (II). Acta Chimica Slovenica, 66(4), 839-849.
