The example of calix[4]pyrrole derivative containing Bodipy unit: Fluorometric and colorimetric sensor for F- ion

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dc.contributor.authorTaner, Bilge
dc.contributor.authorKursunlu, Ahmed Nuri
dc.contributor.authorGuler, Ersin
dc.date.accessioned2020-03-26T18:58:37Z
dc.date.available2020-03-26T18:58:37Z
dc.date.issued2014
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractA novel chemosensor based on calix[4]pyrrole derivative modified by Bodipy unit has been synthesized, and its complexes with various anions were investigated. The results show that the receptors can selectively recognize biologically important fluoride ions. The binding affinity for fluoride ions was investigated by naked-eye color change, absorption, emission, proton nuclear magnetic resonance spectroscopy. The addition of fluoride ions to an acetonitrile solution of chemosensor can result in an obvious color change (brownish yellow color to straw yellow). The stoichiometries between the receptor and fluoride were determined from the molar ratio plots using the UV-visible spectra, which showed evident 1:1. The proton nuclear magnetic resonance spectral data supported the fluoride anion recognition with the disappearance of the amino proton peaks. Published by Elsevier B.V.en_US
dc.description.sponsorshipResearch Foundation of The Selcuk University (BAP)Selcuk University [11101003]en_US
dc.description.sponsorshipWe thank the Research Foundation of The Selcuk University (BAP) for financial support of this work (under Project Number 11101003). The authors express their appreciation to Prof. Ross W. Boyle for helpful discussions.en_US
dc.identifier.doi10.1016/j.saa.2013.09.077en_US
dc.identifier.endpage907en_US
dc.identifier.issn1386-1425en_US
dc.identifier.pmid24161854en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage903en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.saa.2013.09.077
dc.identifier.urihttps://hdl.handle.net/20.500.12395/31207
dc.identifier.volume118en_US
dc.identifier.wosWOS:000328005400120en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherPERGAMON-ELSEVIER SCIENCE LTDen_US
dc.relation.ispartofSPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectCalix[4]pyrroleen_US
dc.subjectBodipyen_US
dc.subjectChemosensoren_US
dc.subjectAnion recognitionen_US
dc.subjectFluoride ionen_US
dc.titleThe example of calix[4]pyrrole derivative containing Bodipy unit: Fluorometric and colorimetric sensor for F- ionen_US
dc.typeArticleen_US

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