The synthesis of N-(2-methylpyridyl)diaminoglyoxime derivates and the formation of their nickel(II) and palladium(II) complexes
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Dosyalar
Tarih
1996
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
MARCEL DEKKER INC
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Unsymmetric glyoximes which contain N-(2-methylpyridyl) on one side and amines or various aromatic amines, respectively, on the other side of the molecule were synthesized. N-(2-Methylpyridyl)aminoglyoxime was chlorinated by employing a method devised by us which is time and solvent dependent, and requires utilization of diethyl ether within a time period of 10-30 minutes. By reacting antichloro-N-(2-methylpyridyl)aminoglyoxime, with ammonia, aniline and benzylamine, respectively, the new ligands synthesized were N-(2-methylpyridyl)diaminoglyoxime (ALH(2)), N-(2-methylpyridyl)-N'-phenyldiaminoglyoxime (BLH(2)) and N-(2-methylpyridyl)-N'-benzyldiaminoglyoxime (CLH(2)). The structure of the ligands were determined employing H-1 NMR, IR spectroscopy and elemental analyses methods. The square-planar complexes of metal-ligand ratio of 1:2 were prepared by addition of Ni(II) and Pd(II) salt solutions into aqueous ligand solutions. The structure of these complexes were characterized by IR spectroscopy, elemental analyses and magnetic susceptibility measurements.
Açıklama
Anahtar Kelimeler
Kaynak
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
WoS Q Değeri
N/A
Scopus Q Değeri
N/A
Cilt
26
Sayı
1
