The synthesis of N-(2-methylpyridyl)diaminoglyoxime derivates and the formation of their nickel(II) and palladium(II) complexes

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dc.contributor.authorKahraman, A
dc.contributor.authorIrez, G
dc.date.accessioned2020-03-26T16:24:53Z
dc.date.available2020-03-26T16:24:53Z
dc.date.issued1996
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractUnsymmetric glyoximes which contain N-(2-methylpyridyl) on one side and amines or various aromatic amines, respectively, on the other side of the molecule were synthesized. N-(2-Methylpyridyl)aminoglyoxime was chlorinated by employing a method devised by us which is time and solvent dependent, and requires utilization of diethyl ether within a time period of 10-30 minutes. By reacting antichloro-N-(2-methylpyridyl)aminoglyoxime, with ammonia, aniline and benzylamine, respectively, the new ligands synthesized were N-(2-methylpyridyl)diaminoglyoxime (ALH(2)), N-(2-methylpyridyl)-N'-phenyldiaminoglyoxime (BLH(2)) and N-(2-methylpyridyl)-N'-benzyldiaminoglyoxime (CLH(2)). The structure of the ligands were determined employing H-1 NMR, IR spectroscopy and elemental analyses methods. The square-planar complexes of metal-ligand ratio of 1:2 were prepared by addition of Ni(II) and Pd(II) salt solutions into aqueous ligand solutions. The structure of these complexes were characterized by IR spectroscopy, elemental analyses and magnetic susceptibility measurements.en_US
dc.identifier.doi10.1080/00945719608004247en_US
dc.identifier.endpage91en_US
dc.identifier.issn0094-5714en_US
dc.identifier.issue1en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage79en_US
dc.identifier.urihttps://dx.doi.org/10.1080/00945719608004247
dc.identifier.urihttps://hdl.handle.net/20.500.12395/16422
dc.identifier.volume26en_US
dc.identifier.wosWOS:A1996TU43400007en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherMARCEL DEKKER INCen_US
dc.relation.ispartofSYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.titleThe synthesis of N-(2-methylpyridyl)diaminoglyoxime derivates and the formation of their nickel(II) and palladium(II) complexesen_US
dc.typeArticleen_US

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