Extraction of carcinogenic aromatic amines from aqueous solution using calix[n]arene derivatives as carrier

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dc.contributor.authorErdemir, Serkan
dc.contributor.authorBahadir, Muefit
dc.contributor.authorYilmaz, Mustafa
dc.date.accessioned2020-03-26T17:38:40Z
dc.date.available2020-03-26T17:38:40Z
dc.date.issued2009
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractThe extraction abilities of p-tert-butylcalix[n]arenes (n = 6, 8) and their carboxylic acid and methyl ester derivatives upon some carcinogenic aromatic amines have been investigated. The separation and quantification of aromatic amines were performed by high-performance liquid chromatography with Ace 5 C-18 column and diode array detection. The optimum pH values for aromatic amines sorption were observed at pH 4.0, 7.0 and 8.5 for all calixarene derivatives. In batch sorption experiments of selected carcinogenic aromatic amines, the experimental results show that octacarboxylic acid derivative of p-tert-butylcalix[8]arene exhibited a better affinity than other compounds towards all aromatic amines species at almost all pHs. The sorption of aromatic amines by carboxylic acid derivatives of p-tert-butylcalix[n]arene indicates that carboxyl groups play the major role for the formation of hydrogen bonds and electrostatic interactions between sorbent and aromatic amine. (C) 2009 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipMinistry of Education and Research (BMBF)Federal Ministry of Education & Research (BMBF); Scientific and Technical Research Council of Turkey (TUBITAK)Turkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [U/118-104T258]; Scientific Research Projects Foundation of the Selcuk University (BAP)Selcuk Universityen_US
dc.description.sponsorshipWe thank the Project Management Organization (DLR) of the German Ministry of Education and Research (BMBF), the Scientific and Technical Research Council of Turkey (TUBITAK), Grant Number U/118-104T258, and the Scientific Research Projects Foundation of the Selcuk University (BAP) for financial support of this work.en_US
dc.identifier.doi10.1016/j.jhazmat.2009.02.150en_US
dc.identifier.endpage1176en_US
dc.identifier.issn0304-3894en_US
dc.identifier.issn1873-3336en_US
dc.identifier.issue02.03.2020en_US
dc.identifier.pmid19345489en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage1170en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.jhazmat.2009.02.150
dc.identifier.urihttps://hdl.handle.net/20.500.12395/23544
dc.identifier.volume168en_US
dc.identifier.wosWOS:000268200700087en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherELSEVIER SCIENCE BVen_US
dc.relation.ispartofJOURNAL OF HAZARDOUS MATERIALSen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectCalixareneen_US
dc.subjectAromatic aminesen_US
dc.subjectCarcinogensen_US
dc.subjectSolid-liquid extractionen_US
dc.subjectHPLCen_US
dc.titleExtraction of carcinogenic aromatic amines from aqueous solution using calix[n]arene derivatives as carrieren_US
dc.typeArticleen_US

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