Effect of the glutaraldehyde derivatives of Calix[n]arene as cross-linker reagents on lipase immobilization

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dc.contributor.authorErdemir, Serkan
dc.contributor.authorSahin, Ozlem
dc.contributor.authorUyanik, Arzu
dc.contributor.authorYilmaz, Mustafa
dc.date.accessioned2020-03-26T17:38:23Z
dc.date.available2020-03-26T17:38:23Z
dc.date.issued2009
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractSynthesis of the glutaraldehyde derivatives calix[n]arene (n = 4,6,8) (Calix[n]-GA) and using as cross-linkers for immobilization of Candida rugosa lipase (CRL) have been discussed in this paper. The amino functional calix[n]arene derivatives (Calix[n]-NH (2)) were synthesized via reduction of dinitrile, hexanitrile and octanitrile derivatives of calix[n]arenes. These amino functional calix[n]arene derivatives (Calix[n]-NH (2)) were converted to their aldehyde derivativatives with glutaraldehyde. The calix[n]arene derivatives were used in lipase immobilization in order to see the role of calix[n]arene binding site on the lipase activitiy and stability. The activity recovery of calix[n]arene-supported lipases (Calix[n]-CRL) based on the Calix[4]-CRL, Calix[6]-CRL and Calix[8]-CRL reaches to 53.5, 66.1 and 76.4%, respectively.en_US
dc.description.sponsorshipThe Research Foundation of Selcuk University (BAP)Selcuk University; The Scientific and Technical Research Council of TurkeyTurkiye Bilimsel ve Teknolojik Arastirma Kurumu (TUBITAK) [106T435]en_US
dc.description.sponsorshipWe would like to thank The Research Foundation of Selcuk University (BAP) and The Scientific and Technical Research Council of Turkey (TUBITAK-Grant Number 106T435) for financial support of this work.en_US
dc.identifier.doi10.1007/s10847-009-9562-5en_US
dc.identifier.endpage282en_US
dc.identifier.issn1388-3127en_US
dc.identifier.issn1573-1111en_US
dc.identifier.issue03.04.2020en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage273en_US
dc.identifier.urihttps://dx.doi.org/10.1007/s10847-009-9562-5
dc.identifier.urihttps://hdl.handle.net/20.500.12395/23463
dc.identifier.volume64en_US
dc.identifier.wosWOS:000267662800009en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSPRINGERen_US
dc.relation.ispartofJOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectCalixareneen_US
dc.subjectCross-linkeren_US
dc.subjectImmobilizationen_US
dc.subjectCandida rugosa lipaseen_US
dc.subjectGlutaraldehydeen_US
dc.titleEffect of the glutaraldehyde derivatives of Calix[n]arene as cross-linker reagents on lipase immobilizationen_US
dc.typeArticleen_US

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