Synthesis of novel ferrocene containing vic-dioxime ligands and their Ni(II), Cu(II) and Co(II) complexes: Spectral, electrochemical and biological activity studies

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dc.contributor.authorDeveci, Pervin
dc.contributor.authorArslan, Ugur
dc.date.accessioned2020-03-26T18:16:28Z
dc.date.available2020-03-26T18:16:28Z
dc.date.issued2011
dc.departmentSelçuk Üniversitesien_US
dc.description.abstractTwo new vic-dioxime ligands bearing an important redox-active substituent, anti-beta-ferrocenylethylaminoglyoxime (1a) and anti-beta-ferrocenylethylaminophenylglyoxime (1b), have been synthesized, and their Ni(II), Cu(II) and Co(II) (2a-4a, 2b-4b) complexes were obtained. The composition and structure of the products were determined by elemental analysis, Fourier transform infrared (FT-IR), ultraviolet-visible (UV-vis), mass spectrometry (MS), one-dimensional (1D) H-1, C-13 NMR, and two-dimensional (2D) heteronuclear multiple bond correlation (HMBC) techniques. The redox behaviors of the ligands and their complexes were investigated by cyclic voltammetry (CV), which revealed that all the ferrocenyl redox centers are electrochemically independent and undergo a quasi-reversible oxidation at similar potentials. Also, antibacterial activity was studied against Staphylococcus aureus ATCC 29213, Streptococcus mutans RSHM 676, Enterococcus faecalis ATCC 29212, Escherichia coli ATCC 25922 and Pseudomonas aeruginosa ATCC 27853. The antimicrobial test results indicated that all the compounds have mild levels of antibacterial activity against both gram negative and gram-positive bacterial species. (C) 2011 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.jorganchem.2011.08.040en_US
dc.identifier.endpage3763en_US
dc.identifier.issn0022-328Xen_US
dc.identifier.issue23en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage3756en_US
dc.identifier.urihttps://dx.doi.org/10.1016/j.jorganchem.2011.08.040
dc.identifier.urihttps://hdl.handle.net/20.500.12395/26874
dc.identifier.volume696en_US
dc.identifier.wosWOS:000296551400025en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherELSEVIER SCIENCE SAen_US
dc.relation.ispartofJOURNAL OF ORGANOMETALLIC CHEMISTRYen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.selcuk20240510_oaigen_US
dc.subjectvic-Dioximeen_US
dc.subjectFerroceneen_US
dc.subjectElectrochemical studyen_US
dc.subjectBiological activityen_US
dc.subjectMetal complexen_US
dc.titleSynthesis of novel ferrocene containing vic-dioxime ligands and their Ni(II), Cu(II) and Co(II) complexes: Spectral, electrochemical and biological activity studiesen_US
dc.typeArticleen_US

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